Enantioselective supramolecular devices in the gas phase. Resorcin[4]arene as a model system
2012 ◽
Vol 8
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pp. 539-550
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Keyword(s):
This review describes the state-of-art in the field of the gas-phase reactivity of diastereomeric complexes formed between a chiral artificial receptor and a biologically active molecule. The presented experimental approach is a ligand-displacement reaction carried out in a nano ESI-FT-ICR instrument, supported by a thermodynamic MS-study and molecular-mechanics and molecular-dynamics (MM/MD) computational techniques. The noncovalent ion–molecule complexes are ideal for the study of chiral recognition in the absence of complicating solvent and counterion effects.
2004 ◽
Vol 121
(21)
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pp. 10467-10473
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2010 ◽
Vol 132
(43)
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pp. 15457-15457
2019 ◽
Vol 21
(26)
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pp. 13959-13967
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2017 ◽
Vol 121
(1)
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pp. 133-140
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