Protonation Equilibrium and Hydrogen Production by a Dinuclear Cobalt–Hydride Complex Reduced by Cobaltocene with Trifluoroacetic Acid

2013 ◽  
Vol 135 (41) ◽  
pp. 15294-15297 ◽  
Author(s):  
Sukanta Mandal ◽  
Shinya Shikano ◽  
Yusuke Yamada ◽  
Yong-Min Lee ◽  
Wonwoo Nam ◽  
...  
1989 ◽  
Vol 366 (3) ◽  
pp. 421-425 ◽  
Author(s):  
V.D. Chinakov ◽  
G.N. Il'inich ◽  
V.N. Zudin ◽  
V.A. Likholobov ◽  
V.M. Nekipelov

2015 ◽  
Vol 44 (33) ◽  
pp. 14646-14655 ◽  
Author(s):  
D. Sirbu ◽  
C. Turta ◽  
E. A. Gibson ◽  
A. C. Benniston

Copper(ii) and palladium(ii) meso-tetraferrocenylporphyrins (CuTFcP and PdTFcP) were employed as catalysts for electrochemical proton reduction in DMF using trifluoroacetic acid (TFA) or triethylamine hydrochloride (TEAHCl) as acids.


2020 ◽  
Vol 49 (16) ◽  
pp. 5064-5073
Author(s):  
Michael Papadakis ◽  
Alexandre Barrozo ◽  
Tatiana Straistari ◽  
Nicolas Queyriaux ◽  
Anisa Putri ◽  
...  

This work reports on the synthesis and characterization of a series of mononuclear thiosemicarbazone nickel complexes that display significant catalytic activity for hydrogen production in DMF using trifluoroacetic acid as the proton source.


2020 ◽  
pp. 124-135
Author(s):  
I. N. G. Wardana ◽  
N. Willy Satrio

Tofu is main food in Indonesia and its waste generally pollutes the waters. This study aims to change the waste into energy by utilizing the electric charge in the pores of tofu waste to produce hydrogen in water. The tofu pore is negatively charged and the surface surrounding the pore has a positive charge. The positive and negative electric charges stretch water molecules that have a partial charge. With the addition of a 12V electrical energy during electrolysis, water breaks down into hydrogen. The test was conducted on pre-treated tofu waste suspension using oxalic acid. The hydrogen concentration was measured by a MQ-8 hydrogen sensor. The result shows that the addition of turmeric together with sodium bicarbonate to tofu waste in water, hydrogen production increased more than four times. This is due to the fact that magnetic field generated by delocalized electron in aromatic ring in turmeric energizes all electrons in the pores of tofu waste, in the sodium bicarbonate, and in water that boosts hydrogen production. At the same time the stronger partial charge in natrium bicarbonate shields the hydrogen proton from strong attraction of tofu pores. These two combined effect are very powerful for larger hydrogen production in water by tofu waste.


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