Metal–Organic Framework-Immobilized Polyhedral Metal Nanocrystals: Reduction at Solid–Gas Interface, Metal Segregation, Core–Shell Structure, and High Catalytic Activity

2013 ◽  
Vol 135 (44) ◽  
pp. 16356-16359 ◽  
Author(s):  
Arshad Aijaz ◽  
Tomoki Akita ◽  
Nobuko Tsumori ◽  
Qiang Xu
Keyword(s):  
Catalytic Activity ◽  
Shell Structure ◽  
Metal Organic Framework ◽  
Core Shell ◽  
High Catalytic Activity ◽  
Metal Nanocrystals ◽  
Metal Organic ◽  
Core Shell Structure ◽  
Organic Framework

scholarly journals Synthesis of a Fe3O4@P4VP@metal–organic framework core–shell structure and studies of its aerobic oxidation reactivity

RSC Advances ◽  
2017 ◽  
Vol 7 (5) ◽  
pp. 2773-2779 ◽  
Author(s):  
Zongcheng Miao ◽  
Xin Shu ◽  
Daniele Ramella
Keyword(s):  
Composite Material ◽  
Shell Structure ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Core Shell ◽  
Oxidation Activity ◽  
Oxidation Reactivity ◽  
Metal Organic ◽  
Core Shell Structure ◽  
Organic Framework

A novel core–shell magnetic Fe3O4@P4VP@MIL-100(Fe) composite material has been synthesized and its aerobic oxidation activity has been extensively studied.

Metal–organic framework derived copper catalysts for CO2 to ethylene conversion

2020 ◽  
Vol 8 (22) ◽  
pp. 11117-11123 ◽  
Author(s):  
Kaili Yao ◽  
Yujian Xia ◽  
Jun Li ◽  
Ning Wang ◽  
Jingrui Han ◽  
...  
Keyword(s):  
Surface Reconstruction ◽  
Shell Structure ◽  
Metal Organic Framework ◽  
Copper Catalysts ◽  
Core Shell ◽  
Ethylene Conversion ◽  
Metal Organic ◽  
Core Shell Structure ◽  
Organic Framework

MOF-derived copper catalysts underwent a surface reconstruction to form a Cu@CuxO core@shell structure during CO2RR process, which was beneficial for CO2 to C2H4 conversion, resulting in a 51% FE for C2H4 and 70% FE for C2+ products.

Highly selective separation of H2S and CO2 using a H2S-imprinted polymers loaded on a polyoxometalate@Zr-based metal–organic framework with a core–shell structure at ambient temperature

2019 ◽  
Vol 7 (19) ◽  
pp. 12105-12114 ◽  
Author(s):  
Yan Huang ◽  
Rui Wang
Keyword(s):  
Ambient Temperature ◽  
Shell Structure ◽  
Metal Organic Framework ◽  
Resource Recovery ◽  
Selective Separation ◽  
Core Shell ◽  
Imprinted Polymers ◽  
Metal Organic ◽  
Core Shell Structure ◽  
Organic Framework

Core–shell-structured H2S imprinted polymers loaded on polyoxometalate@UiO-66 achieved highly effective H2S/CO2 separation and sulfur resource recovery.

A metal–organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst for photodriven hydrogen production

2020 ◽  
Vol 56 (49) ◽  
pp. 6700-6703
Author(s):  
Ning-Yu Huang ◽  
Hai He ◽  
Hao Li ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Binuclear Copper ◽  
Metal Organic ◽  
Cu Ions ◽  
Organic Framework

Here, we report a metal–organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g−1 h−1) for photodriven H2 generation, which is attributed to the synergistic effect between the two Cu ions.

Cobalt nanoparticle-embedded nitrogen-doped carbon/carbon nanotube frameworks derived from a metal–organic framework for tri-functional ORR, OER and HER electrocatalysis

2019 ◽  
Vol 7 (8) ◽  
pp. 3664-3672 ◽  
Author(s):  
Hele Guo ◽  
Qichun Feng ◽  
Jixin Zhu ◽  
Jingsan Xu ◽  
Qianqian Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbon Nanotube ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Nitrogen Doped ◽  
Metal Organic ◽  
Nitrogen Doped Carbon ◽  
Cobalt Nanoparticle ◽  
Organic Framework

A Co@N-CNTF electrocatalyst derived from a metal–organic framework exhibits high catalytic activity in the ORR, OER and HER.

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