scholarly journals Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

2014 ◽  
Vol 136 (33) ◽  
pp. 11574-11577 ◽  
Author(s):  
Daniël L. J. Broere ◽  
Bas de Bruin ◽  
Joost N. H. Reek ◽  
Martin Lutz ◽  
Sebastian Dechert ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Radical Reactivity ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Tin(II)–Nitrene Radical Complexes Formed by Electron Transfer from Redox-Active Ligand to Organic Azides and Their Reactivity in C(sp3)–H Activation

2021 ◽  
Author(s):  
Hideki Sugimoto ◽  
Mayuka Yano ◽  
Kazunobu Sato ◽  
Mayuko Miyanishi ◽  
Kenji Sugisaki ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Organic Azides ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Actinide Redox-Active Ligand Complexes: Reversible Intramolecular Electron-Transfer in U(dpp-BIAN)2/U(dpp-BIAN)2(THF)

2010 ◽  
Vol 49 (3) ◽  
pp. 924-933 ◽  
Author(s):  
Eric J. Schelter ◽  
Ruilian Wu ◽  
Brian L. Scott ◽  
Joe D. Thompson ◽  
Thibault Cantat ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Intramolecular Electron Transfer ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Aminotroponiminates as tunable, redox-active ligands: reversible single electron transfer and reductive dimerisation

2016 ◽  
Vol 52 (65) ◽  
pp. 10044-10047 ◽  
Author(s):  
C. Lichtenberg ◽  
I. Krummenacher
Keyword(s):  
Electron Transfer ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Redox Active Ligands ◽  
Redox Active

Aminotroponiminates are shown to be redox-active ligands with their properties being tunable by choice of the ligand-bound metal.

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

Ultrafast optical switching at the telecommunication wavelength by single electron transfer between fluorene-containing redox polymer and its counter anion

2004 ◽  
Vol 85 (16) ◽  
pp. 3444-3446 ◽  
Author(s):  
Toshihiko Nagamura ◽  
Yasuyuki Nagai ◽  
Akihiro Furube ◽  
Shigeo Murata
Keyword(s):  
Electron Transfer ◽  
Optical Switching ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Counter Anion ◽  
Redox Polymer ◽  
Ultrafast Optical ◽  
Telecommunication Wavelength

Oxidative and Redox‐Neutral Approaches to Symmetrical Diamines and Diols by Single Electron Transfer/Hydrogen Atom Transfer Synergistic Catalysis

2020 ◽  
Vol 2020 (46) ◽  
pp. 7151-7155 ◽  
Author(s):  
Masashi Fujita ◽  
Fumihisa Kobayashi ◽  
Takafumi Ide ◽  
Hiromichi Egami ◽  
Yoshitaka Hamashima
Keyword(s):  
Electron Transfer ◽  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Single Electron ◽  
Atom Transfer ◽  
Single Electron Transfer ◽  
Synergistic Catalysis

Reactivity of Aluminum Complexes of Redox-Active Ligand toward N-Heterocyclic Carbene and Its Thione

2019 ◽  
Vol 39 (1) ◽  
pp. 66-73 ◽  
Author(s):  
Vladimir G. Sokolov ◽  
Tatyana S. Koptseva ◽  
Roman V. Rumyantcev ◽  
Xiao-Juan Yang ◽  
Yanxia Zhao ◽  
...  
Keyword(s):  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Aluminum Complexes

POSSIBILITY OF MOLECULAR-SWITCH WITH CONTROLLED HYDROGEN BOND: UTILITY OF COMBINATION OF 2,2′-BIIMIDAZOLE AND REDOX-ACTIVE LIGAND

2005 ◽  
Vol 04 (01) ◽  
pp. 333-344 ◽  
Author(s):  
HIROTOSHI MORI ◽  
EISAKU MIYOSHI
Keyword(s):  
Density Functional ◽  
Molecular Level ◽  
Molecular Switch ◽  
Vibration Band ◽  
Functional Theory ◽  
Inorganic Molecule ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Stretching Vibration

A new inorganic molecule [ Co(Hbim) ( C 6 H 4 O 2)( NH 3)2]2 that can be used as a new optically durable molecular switch was theoretically designed in the framework of density functional theory. Three stable minima, belonging to 1 A g , 5 A 1, and 9 A g states, were found in the complex. Theoretically predicted infrared spectra of the complexes showed that a strong peak of NH stretching vibration is observed at 2690, 2120, and 2770 cm -1 in the 1 A g , 5 A 1, and 9 A g states, respectively. The apparent red shift of the NH stretching vibration band in the 5 A 1 state make it possible to distinguish the electronic state from others (1 A g and 9 A g ). This means that the complex can be used as a molecular level switch whose memory can be stably read by IR light without any photoreaction process; namely, without memory degradation.

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