On-Wire Conversion Chemistry: Engineering Solid-State Complexity into Striped Metal Nanowires using Solution Chemistry Reactions

2008 ◽  
Vol 130 (43) ◽  
pp. 14042-14043 ◽  
Author(s):  
Mary E. Anderson ◽  
Matthew R. Buck ◽  
Ian T. Sines ◽  
Karl D. Oyler ◽  
Raymond E. Schaak
Keyword(s):  
Solid State ◽  
Solution Chemistry ◽  
Metal Nanowires ◽  
State Complexity

Solid-state and solution chemistry of calcium N-(phosphonomethyl)glycinate

1988 ◽  
Vol 27 (6) ◽  
pp. 1056-1061 ◽  
Author(s):  
Paul H. Smith ◽  
Kenneth N. Raymond
Keyword(s):  
Solid State ◽  
Solution Chemistry

The Formation of Green Rust and Its Transformation to Lepidocrocite

Clay Minerals ◽  
1994 ◽  
Vol 29 (1) ◽  
pp. 87-92 ◽  
Author(s):  
U. Schwertmann ◽  
H. Fechter
Keyword(s):  
Solid State ◽  
Reaction Rate ◽  
Green Rust ◽  
Solution Chemistry ◽  
Subsequent Transformation ◽  
Constant Ph ◽  
Temperature Constant ◽  
A Minor ◽  
Complete Transformation ◽  
The Ideal

AbstractThe formation of FeII,III hydoxy salts (green rusts) from FeII sulphate and chloride solutions and their transformation to lepidocrocite, γ-FeOOH, was studied at ambient temperature, constant pH of ∼7.0 and under controlled air flow. The formation of green rust and its subsequent transformation to lepidocrocite could be distinguished by the reaction rate and solution chemistry. The SO42− and Cl− concentrations in solution attain a minimum at the break between the two reaction steps and are completely restored to their initial values after complete transformation to lepidocrocite. While the green rust is being formed, its FeII/FeIII ratio shows a minor decrease and its FeIII/anion ratio a minor increase. These ratios, however, deviate from the ideal pyroaurite-type structure (M2+/M3+ = 3; M3+/A− = 1; M: metal; A−: anion) and possibilities to accommodate this deviation are discussed. A period during which no protons were produced (i.e. no base consumed) was found to separate the two reactions in the chloride, but not in the sulphate system. During this period a partial solid state oxidation of the green rust took place, leading to its destabilization and eventual decomposition.

The First Electronically Stabilized Phenalenyl Radical:  Effect of Substituents on Solution Chemistry and Solid-State Structure

2007 ◽  
Vol 7 (4) ◽  
pp. 802-809 ◽  
Author(s):  
Leanne Beer ◽  
Swadhin K. Mandal ◽  
Robert W. Reed ◽  
Richard T. Oakley ◽  
Fook S. Tham ◽  
...  
Keyword(s):  
Solid State ◽  
Solution Chemistry ◽  
State Structure ◽  
Solid State Structure ◽  
Effect Of Substituents
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