Metal−Metal Bonding in Rh2(O2CCF3)4:  Extensive Metal−Ligand Orbital Mixing Promoted by Filled Fluorine Orbitals

2000 ◽  
Vol 122 (13) ◽  
pp. 3182-3190 ◽  
Author(s):  
Dennis L. Lichtenberger ◽  
John R. Pollard ◽  
Matthew A. Lynn ◽  
F. A. Cotton ◽  
Xuejun Feng
Keyword(s):  
Metal Bonding ◽  
Metal Metal ◽  
Ligand Orbital ◽  
Orbital Mixing ◽  
Metal Ligand

scholarly journals Syntheses, spectroscopic, redox, and structural properties of homoleptic Iron(III/II) dithione complexes

RSC Advances ◽  
2020 ◽  
Vol 10 (63) ◽  
pp. 38294-38303
Author(s):  
Kyle J. Colston ◽  
Sara A. Dille ◽  
Benjamin Mogesa ◽  
Jacilynn Brant ◽  
Victor N. Nemykin ◽  
...  
Keyword(s):  
Structural Properties ◽  
Ligand Orbital ◽  
Orbital Mixing ◽  
Metal Ligand

Two sets of FeIII/II complexes, synthesized from N,N′-diisopropyl piperazine-2,3-dithione (iPr2Dt0) and N,N′-dimethyl piperazine-2,3-dithione (Me2Dt0) ligands, exhibit electronically asymmetrical ligands with metal–ligand orbital mixing.

An Estimation Method of Metal-Ligand Orbital Mixing in Lanthanide(III) Complexes Using Magnetic Circular Dichroism

2018 ◽  
Vol 3 (9) ◽  
pp. 2646-2648 ◽  
Author(s):  
Yuichi Kitagawa ◽  
Takayuki Nakanishi ◽  
Koji Fushimi ◽  
Yasuchika Hasegawa
Keyword(s):  
Circular Dichroism ◽  
Magnetic Circular Dichroism ◽  
Estimation Method ◽  
Ligand Orbital ◽  
Orbital Mixing ◽  
Circular Dichroïsm ◽  
Metal Ligand

scholarly journals Metal-ligand and metal-metal bonding characterization from X-ray diffraction

2005 ◽  
Vol 61 (a1) ◽  
pp. c311-c311
Author(s):  
N. Bouhmaida ◽  
B. Fraisse ◽  
A. Perez-Benítez ◽  
M. A. Méndez-Rojas ◽  
N. E. Ghermani
Keyword(s):  
X Ray Diffraction ◽  
X Ray ◽  
Metal Bonding ◽  
Metal Metal ◽  
Metal Ligand

Metal-metal bonding and mixed-valent tantalum in La2Ta3S2O8

1992 ◽  
Vol 98 (1) ◽  
pp. 82-89 ◽  
Author(s):  
Theodore D. Brennan ◽  
James A. Ibers
Keyword(s):  
Metal Bonding ◽  
Metal Metal

MC4:  A Hypothetical Three-Dimensional Organometallic Net with Metal−Metal Bonding and Polyacetylene Substructures

1996 ◽  
Vol 118 (42) ◽  
pp. 10294-10302 ◽  
Author(s):  
Norman Goldberg ◽  
Huang Tang ◽  
Nancy Kroohs ◽  
Roald Hoffmann
Keyword(s):  
Three Dimensional ◽  
Metal Bonding ◽  
Metal Metal
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