ChemInform Abstract: Trends in Metal-Ligand Orbital Mixing in Generic Series of Ruthenium N-Donor Ligand Complexes - Effect on Electronic Spectra and Redox Properties

ChemInform ◽  
2010 ◽  
Vol 30 (4) ◽  
pp. no-no
Author(s):  
S. I. Gorelsky ◽  
E. S. Dodsworth ◽  
A. B. P. Lever ◽  
A. A. Vlcek
Keyword(s):  
Electronic Spectra ◽  
Redox Properties ◽  
Donor Ligand ◽  
Ligand Orbital ◽  
Orbital Mixing ◽  
Metal Ligand

scholarly journals Syntheses, spectroscopic, redox, and structural properties of homoleptic Iron(III/II) dithione complexes

RSC Advances ◽  
2020 ◽  
Vol 10 (63) ◽  
pp. 38294-38303
Author(s):  
Kyle J. Colston ◽  
Sara A. Dille ◽  
Benjamin Mogesa ◽  
Jacilynn Brant ◽  
Victor N. Nemykin ◽  
...  
Keyword(s):  
Structural Properties ◽  
Ligand Orbital ◽  
Orbital Mixing ◽  
Metal Ligand

Two sets of FeIII/II complexes, synthesized from N,N′-diisopropyl piperazine-2,3-dithione (iPr2Dt0) and N,N′-dimethyl piperazine-2,3-dithione (Me2Dt0) ligands, exhibit electronically asymmetrical ligands with metal–ligand orbital mixing.

Metal−Metal Bonding in Rh2(O2CCF3)4:  Extensive Metal−Ligand Orbital Mixing Promoted by Filled Fluorine Orbitals

2000 ◽  
Vol 122 (13) ◽  
pp. 3182-3190 ◽  
Author(s):  
Dennis L. Lichtenberger ◽  
John R. Pollard ◽  
Matthew A. Lynn ◽  
F. A. Cotton ◽  
Xuejun Feng
Keyword(s):  
Metal Bonding ◽  
Metal Metal ◽  
Ligand Orbital ◽  
Orbital Mixing ◽  
Metal Ligand

An Estimation Method of Metal-Ligand Orbital Mixing in Lanthanide(III) Complexes Using Magnetic Circular Dichroism

2018 ◽  
Vol 3 (9) ◽  
pp. 2646-2648 ◽  
Author(s):  
Yuichi Kitagawa ◽  
Takayuki Nakanishi ◽  
Koji Fushimi ◽  
Yasuchika Hasegawa
Keyword(s):  
Circular Dichroism ◽  
Magnetic Circular Dichroism ◽  
Estimation Method ◽  
Ligand Orbital ◽  
Orbital Mixing ◽  
Circular Dichroïsm ◽  
Metal Ligand

Controlling Near-Infrared Chromophore Electronic Properties through Metal–Ligand Orbital Alignment

2017 ◽  
Vol 139 (7) ◽  
pp. 2808-2815 ◽  
Author(s):  
Nicole M. Mews ◽  
Andreas Berkefeld ◽  
Gerald Hörner ◽  
Hartmut Schubert
Keyword(s):  
Electronic Properties ◽  
Near Infrared ◽  
Ligand Orbital ◽  
Metal Ligand

Redox properties of thiolate-bridged binuclear nickel(II) complexes and correlation of their electronic spectra

1991 ◽  
Vol 16 (5) ◽  
pp. 532-534 ◽  
Author(s):  
Masahiro Mikuriya ◽  
Shinji Shigematsu ◽  
Makoto Handa ◽  
Takamitsu Kohzuma
Keyword(s):  
Electronic Spectra ◽  
Redox Properties

Dimethyl Phthalate, a Neutral Bidentate Oxygen-Donor Ligand to Divalent Metal Ions

1977 ◽  
Vol 32 (11) ◽  
pp. 1284-1286 ◽  
Author(s):  
W. L. Driessen ◽  
P. L. A. Everstijn
Keyword(s):  
Metal Ions ◽  
Divalent Metal ◽  
Dimethyl Phthalate ◽  
Divalent Metal Ions ◽  
Melting Points ◽  
Bending Vibration ◽  
Donor Ligand ◽  
Oxygen Donor ◽  
Stretching Vibration ◽  
Metal Ligand

A series of new coordination compounds is reported with dimethyl phthalate (MPH) as the ligand, viz. [M(MPH)3](InCl4)2 with M=Mg(II), Ca(II), Mn(II), Fe(II), Co(II), Ni(II), and Zn(II). Each of the metal ions is bonded to three dimethyl phthalate molecules, the six carbonyl oxygens forming a regular octahedron. The carbonyl stretching vibration shifts to lower frequencies, the carbonyl bending vibration shifts to higher frequencies. The magnitudes of the shifts of these vibrations, the frequencies of the metal-ligand vibrations, and the melting points follow the Irving-Williams sequence.

Sign in / Sign up

Export Citation Format

Share Document