Covalent vs Charge-Shift Nature of the Metal–Metal Bond in Transition Metal Complexes: A Unified Understanding

2020 ◽  
Vol 142 (28) ◽  
pp. 12277-12287 ◽  
Author(s):  
Jyothish Joy ◽  
David Danovich ◽  
Martin Kaupp ◽  
Sason Shaik
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Metal Bond ◽  
Metal Metal ◽  
Charge Shift

Planare Dicarbonylrhodium(I)- und -iridium(I) -Komplexe mit polarisierbaren aromatischen Liganden / Planar Dicarbonylrhodium(I) and Iridium(I) Complexes with Polarizable Aromatic Ligands

1973 ◽  
Vol 28 (3-4) ◽  
pp. 164-167 ◽  
Author(s):  
Rolf Aderjan ◽  
Hermann Breer ◽  
Heimo J. Keller ◽  
Herbert H. Rupp
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
General Type ◽  
Analytical Data ◽  
Metal Interactions ◽  
Metal Metal ◽  
Pmr Spectra

Some new transition metal complexes of the general type M(CO)2(L-L), where M stands for Ir(I), Rh(I) and L-L for a bidentate mononegative ligand are described. They were characterized by means of analytical data and their IR and PMR spectra. The chemical and solid state properties of these compounds are related to the strength of the intermolecular metal-metal interactions.

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