Effect of Temperature on Phase Equilibrium of the Mixed-Solvent System of (2,2,2-Trifluoroethanol + Methanol + Cyclohexane)†

2009 ◽  
Vol 54 (2) ◽  
pp. 282-285 ◽  
Author(s):  
Zadjia Atik ◽  
Wahiba Kerboub
Author(s):  
Anis Ahmed Sheikh ◽  
Syed U.K. Asema ◽  
Mohamad Asif ◽  
Shaukat Patel

The density and Viscosity of Ethanol-Water mixed solvent systems (5%, 10%, 20% ,40% v/v ) has been determined at 298,303,308 and 313 K. The same parameters has been determined for the KCl-Ethanol-Water mixture (2%, 4%, 6%, 8%, 10% w/v)The results obtained from these determinations were discussed. The effect of temperature and KCl electrolyte on density and viscosity of mixed solvent systems and mixture has been studied. The increase in temperature of mixed solvent system results in decrease in density and Viscosity. But with the addition of KCl electrolyte in mixed solvent system results in increase in density and viscosity at constant temperature but the same parameters decrease when temperature increases. The variation of these parameters is due to solute-solvent and solvent-solvent interaction.


1998 ◽  
Vol 39 (4) ◽  
pp. 291-312 ◽  
Author(s):  
J.S. Church ◽  
A.S. Davie ◽  
P.J. Scammells ◽  
D.J. Tucker

2021 ◽  
Vol 60 (39) ◽  
pp. 14026-14037
Author(s):  
Nurul Nadiah Abd Razak ◽  
Lai Ti Gew ◽  
Yolande Pérès ◽  
Patrick Cognet ◽  
Mohamed Kheireddine Aroua

2003 ◽  
Vol 56 (5) ◽  
pp. 423 ◽  
Author(s):  
José A. C. Alves ◽  
Amadeu F. Brigas ◽  
Robert A. W. Johnstone

Adsorption isotherms in the liquid phase can be used to determine the relative strengths of adsorption of reactants and solvent at a catalyst surface. Such isotherms can then be used to indicate which type of solvent would be most suitable for a heterogeneously catalyzed reaction in the liquid-phase. Solubility in any chosen solvent is also important. As examples, rates of heterogeneously catalyzed liquid-phase transfer hydrogenolyzes of aryl tetrazolyl ethers (1) have been shown to be highly dependent on both the nature of the solvent and on the solution concentrations of the reactants. The rate of reaction can be varied from zero to a maximum and then back to zero simply by adjusting the solubility of the reductant through changes in the proportion of water in a mixed-solvent system.


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