.alpha.,.beta.-Epoxy sulfoxides as useful intermediates in organic synthesis. 22. Stereospecific desulfinylation of sulfinylaziridines with alkylmetals: a novel synthesis including asymmetric synthesis of (Z)-N-arylaziridines and some mechanistic studies

1989 ◽  
Vol 54 (16) ◽  
pp. 3973-3978 ◽  
Author(s):  
Tsuyoshi Satoh ◽  
Takahiko Sato ◽  
Teruhiko Oohara ◽  
Koji Yamakawa
Keyword(s):  
Asymmetric Synthesis ◽  
Organic Synthesis ◽  
Mechanistic Studies ◽  
Novel Synthesis ◽  
Alpha Beta

ChemInform Abstract: Free Radicals in Organic Synthesis. A Novel Synthesis of Ethylene Glycol Based on Formaldehyde.

ChemInform ◽  
1988 ◽  
Vol 19 (2) ◽  
Author(s):  
J. R. SANDERSON ◽  
E. L. YEAKEY ◽  
J. J. LIN ◽  
R. G. DURANLEAU ◽  
E. T. MARQUIS
Keyword(s):  
Free Radicals ◽  
Ethylene Glycol ◽  
Organic Synthesis ◽  
Novel Synthesis

scholarly journals Cu/Pd-catalyzed borocarbonylative trifunctionalization of alkynes and allenes: synthesis of β-geminal-diboryl ketones

2021 ◽  
Author(s):  
Yang Yuan ◽  
Fu-Peng Wu ◽  
Anke Spannenberg ◽  
Xiao-Feng Wu
Keyword(s):  
Organic Synthesis ◽  
Functional Group ◽  
Building Blocks ◽  
Mechanistic Studies ◽  
Efficient Strategy ◽  
New Class ◽  
Reaction Proceeds

AbstractFunctionalized bisboryl compounds have recently emerged as a new class of synthetically useful building blocks in organic synthesis. Herein, we report an efficient strategy to synthesize β-geminal-diboryl ketones enabled by a Cu/Pd-catalyzed borocarbonylative trifunctionalization of readily available alkynes and allenes. This reaction promises to be a useful method for the synthesis of functionalized β-geminal-diboryl ketones with broad functional group tolerance. Mechanistic studies suggest that the reaction proceeds through borocarbonylation/hydroboration cascade of both alkynes and allenes.

scholarly journals Silyl Nitronates in Organic Synthesis. Silylation of Secondary Nitro Compounds. Preparation of Nitroso Compounds and alpha,beta-Unsaturated Aldehydes.

1981 ◽  
Vol 35b ◽  
pp. 643-648 ◽  
Author(s):  
Somir K. Mukerji ◽  
Kurt B. G. Torssell ◽  
Christina Ullenius ◽  
Povl Krogsgaard-Larsen ◽  
Ulrika Örn
Keyword(s):  
Organic Synthesis ◽  
Nitro Compounds ◽  
Nitroso Compounds ◽  
Unsaturated Aldehydes ◽  
Silyl Nitronates ◽  
Alpha Beta
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