Lithium Aluminum Hydride Reactions in Pyridine Solution. II. The Role of Steric Effects in the Reductive Cleavage of Pinacolones

1961 ◽  
Vol 26 (7) ◽  
pp. 2277-2280 ◽  
Author(s):  
PETER T. LANSBURY ◽  
JOHN R. ROGOZINSKI ◽  
FAY L. COBLENTZ
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Reductive Cleavage ◽  
Steric Effects ◽  
Lithium Aluminum ◽  
Pyridine Solution

scholarly journals The Formation of Lysolecithin by Reductive Cleavage of Egg Yolk Lecithin with Lithium Aluminum Hydride

1963 ◽  
Vol 36 (8) ◽  
pp. 1049-1050 ◽  
Author(s):  
Chieko Urakami ◽  
Kimiko Yamaguchi
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Egg Yolk ◽  
Reductive Cleavage ◽  
Lithium Aluminum

ChemInform Abstract: REDUCTIVE CLEAVAGE OF PHOSPHINANILIDES WITH LITHIUM ALUMINUM HYDRIDE

1974 ◽  
Vol 5 (46) ◽  
pp. no-no
Author(s):  
P. D. HENSON ◽  
S. B. OCKRYMIEK ◽  
R. E. JUN. MARKHAM
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Reductive Cleavage ◽  
Lithium Aluminum

THE SYNTHESIS OF SOME INDOLYLALKYLAMINOALCOHOLS

1960 ◽  
Vol 38 (9) ◽  
pp. 1434-1438 ◽  
Author(s):  
Gerassimos Frangatos ◽  
Geza Kohan ◽  
Francis L. Chubb
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Reductive Cleavage ◽  
Lithium Aluminum ◽  
Carbonyl Groups ◽  
Open Chain ◽  
Hydride Reduction

A series of 3-indolylalkylaminoalcohols have been obtained from the lithium aluminum hydride reduction of the amides prepared by the reaction of 3-indoleglyoxylyl chloride and 2-methyl-3-indoleglyoxylyl chloride with primary aminoalcohols. When acetone was used as solvent in the reaction of 3-indoleglyoxylyis chloride and either 2-aminoethanol or 3-aminopropanol, the solvent participated in the reaction resulting in the formation of 2,2-dimethyl-3-(3-indoleglyoxyl)oxazolidine and 2,2-dimethyl-3-(3-indoleglyoxyl)tetrahydro-1,3-oxazine respectively. When the latter two compounds were reduced by lithium aluminum hydride, both carbonyl groups were completely reduced and reductive cleavage of the oxazolidine and tetrahydro-1,3-oxazine rings occurred to form the corresponding open-chain alcohols.

ChemInform Abstract: Selective Reductive Cleavage of Esters Using Lithium Aluminum Hydride.

ChemInform ◽  
2010 ◽  
Vol 27 (31) ◽  
pp. no-no
Author(s):  
M. M. JOSEPH ◽  
E. D. JACOB
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Reductive Cleavage ◽  
Lithium Aluminum
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