Nucleophilic Displacement Reactions in Ionic Liquids:  Substrate and Solvent Effect in the Reaction of NaN3and KCN with Alkyl Halides and Tosylates†

2003 ◽  
Vol 68 (17) ◽  
pp. 6710-6715 ◽  
Author(s):  
Cinzia Chiappe ◽  
Daniela Pieraccini ◽  
Paola Saullo
Keyword(s):  
Ionic Liquids ◽  
Solvent Effect ◽  
Alkyl Halides ◽  
Nucleophilic Displacement ◽  
Displacement Reactions

ChemInform Abstract: Ionic Liquids as Catalytic Green Solvents for Nucleophilic Displacement Reactions.

ChemInform ◽  
2010 ◽  
Vol 32 (36) ◽  
pp. no-no
Author(s):  
Christy Wheeler ◽  
Kevin N. West ◽  
Charles L. Liotta ◽  
Charles A. Eckert
Keyword(s):  
Ionic Liquids ◽  
Green Solvents ◽  
Nucleophilic Displacement ◽  
Displacement Reactions

Ionic liquids as catalytic green solvents for nucleophilic displacement reactions

2001 ◽  
pp. 887-888 ◽  
Author(s):  
Christy Wheeler ◽  
Kevin N. West ◽  
Charles A. Eckert ◽  
Charles L. Liotta
Keyword(s):  
Ionic Liquids ◽  
Green Solvents ◽  
Nucleophilic Displacement ◽  
Displacement Reactions

Mechanistic comparison of β-H elimination, β-OH elimination, and nucleophilic displacement reactions of β-hydroxy alkyl rhodium porphyrin complexes

2011 ◽  
Vol 40 (10) ◽  
pp. 2213-2217 ◽  
Author(s):  
Bing Wu ◽  
Jiadi Zhang ◽  
Lin Yun ◽  
Xuefeng Fu
Keyword(s):  
Nucleophilic Displacement ◽  
Displacement Reactions

Organic reactions in ionic liquids: N-alkylation of cyclic imides with alkyl halides promoted by potassium fluoride

2004 ◽  
Vol 2004 (4) ◽  
pp. 276-278 ◽  
Author(s):  
Yi Hu ◽  
Zhen-Chu Chen ◽  
Zhang-Gao Le ◽  
Qin-Guo Zheng
Keyword(s):  
Ionic Liquids ◽  
Potassium Fluoride ◽  
Alkyl Halides ◽  
Organic Reactions ◽  
Cyclic Imides

The gas phase reactivity of the dimethylchloronium ion with alkylbenzenes

1981 ◽  
Vol 59 (15) ◽  
pp. 2412-2416 ◽  
Author(s):  
John A. Stone ◽  
Margaret S. Lin ◽  
Jeffrey Varah
Keyword(s):  
High Pressure ◽  
Gas Phase ◽  
Mass Spectrometer ◽  
Aromatic Hydrocarbons ◽  
Relative Rate ◽  
Ion Source ◽  
Nucleophilic Displacement ◽  
Rate Of Reaction ◽  
Displacement Reactions ◽  
Bonded Complexes

The reactivity of the dimethylchloronium ion with a series of aromatic hydrocarbons has been studied in a high pressure mass spectrometer ion source using the technique of reactant ion monitoring. Benzene is unreactive but all others, from toluene to mesitylene, react by CH3+ transfer to yield σ-bonded complexes. The relative rate of reaction increases with increasing exothermicity in line with current theories of nucleophilic displacement reactions.

Ionic liquid as an efficient promoting medium for two-phase nucleophilic displacement reactions

Tetrahedron ◽  
2003 ◽  
Vol 59 (6) ◽  
pp. 789-794 ◽  
Author(s):  
Nuno M.T Lourenço ◽  
Carlos A.M Afonso
Keyword(s):  
Ionic Liquid ◽  
Two Phase ◽  
Nucleophilic Displacement ◽  
Displacement Reactions
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