Dynamic Kinetic Resolution Based Asymmetric Transfer Hydrogenation of α-Alkoxy-β-Ketophosphonates. Diastereo- and Enantioselective Synthesis of Monoprotected 1,2-Dihydroxyphosphonates

2014 ◽  
Vol 79 (6) ◽  
pp. 2666-2681 ◽  
Author(s):  
Se-Mi Son ◽  
Hyeon-Kyu Lee
Keyword(s):  
Kinetic Resolution ◽  
Enantioselective Synthesis ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution

Enantioselective synthesis of chiral multicyclic γ-lactones via dynamic kinetic resolution of racemic γ-keto carboxylic acids

2020 ◽  
Vol 7 (1) ◽  
pp. 104-108 ◽  
Author(s):  
Zhichao Xiong ◽  
Jiangyan Tian ◽  
Peng Xue ◽  
Xumu Zhang ◽  
Hui Lv
Keyword(s):  
Carboxylic Acids ◽  
Kinetic Resolution ◽  
Enantioselective Synthesis ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
High Yields

Ru-Catalyzed asymmetric transfer hydrogenation of γ-keto carboxylic acids has been achieved, affording chiral multicyclic γ-lactones in high yields with excellent diastereo- and enantioselectivities.

scholarly journals trans-Diastereoselective Ru(II)-Catalyzed Asymmetric Transfer Hydrogenation of α-Acetamido Benzocyclic Ketones via Dynamic Kinetic Resolution

2019 ◽  
Vol 21 (10) ◽  
pp. 3644-3648 ◽  
Author(s):  
Andrej Emanuel Cotman ◽  
Matic Lozinšek ◽  
Baifan Wang ◽  
Michel Stephan ◽  
Barbara Mohar
Keyword(s):  
Kinetic Resolution ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution
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