Enantioselective synthesis of chiral multicyclic γ-lactones via dynamic kinetic resolution of racemic γ-keto carboxylic acids

2020 ◽  
Vol 7 (1) ◽  
pp. 104-108 ◽  
Author(s):  
Zhichao Xiong ◽  
Jiangyan Tian ◽  
Peng Xue ◽  
Xumu Zhang ◽  
Hui Lv
Keyword(s):  
Carboxylic Acids ◽  
Kinetic Resolution ◽  
Enantioselective Synthesis ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
High Yields

Ru-Catalyzed asymmetric transfer hydrogenation of γ-keto carboxylic acids has been achieved, affording chiral multicyclic γ-lactones in high yields with excellent diastereo- and enantioselectivities.

Stereogenic cis-2-substituted-N-acetyl-3-hydroxy-indolines via ruthenium(ii)-catalyzed dynamic kinetic resolution-asymmetric transfer hydrogenation

2018 ◽  
Vol 54 (96) ◽  
pp. 13503-13506 ◽  
Author(s):  
Zhonghua Luo ◽  
Guodong Sun ◽  
Zihong Zhou ◽  
Guozhu Liu ◽  
Baolei Luan ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
High Yields

Ruthenium(ii)-catalyzed dynamic kinetic resolution-asymmetric transfer hydrogenation of racemic 2-substituted-N-acetyl-3-oxoindolines is reported, affording cis-2-substituted-N-acetyl-3-hydroxyindolines in high yields with excellent diastereoselectivity and enantioselectivity.

scholarly journals trans-Diastereoselective Ru(II)-Catalyzed Asymmetric Transfer Hydrogenation of α-Acetamido Benzocyclic Ketones via Dynamic Kinetic Resolution

2019 ◽  
Vol 21 (10) ◽  
pp. 3644-3648 ◽  
Author(s):  
Andrej Emanuel Cotman ◽  
Matic Lozinšek ◽  
Baifan Wang ◽  
Michel Stephan ◽  
Barbara Mohar
Keyword(s):  
Kinetic Resolution ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution
Sign in / Sign up

Export Citation Format

Share Document