Chemoselective Transfer Hydrogenation of α,β-Unsaturated Aldehydes to Allylic Alcohols Using Formic Acid Catalyzed by Polymer-Bound Rh Carbonyl Clusters

1998 ◽  
Vol 63 (7) ◽  
pp. 2378-2381 ◽  
Author(s):  
Tomoo Mizugaki ◽  
Yoshinori Kanayama ◽  
Kohki Ebitani ◽  
Kiyotomi Kaneda
Keyword(s):  
Formic Acid ◽  
Transfer Hydrogenation ◽  
Allylic Alcohols ◽  
Carbonyl Clusters ◽  
Unsaturated Aldehydes ◽  
Acid Catalyzed

Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols

2020 ◽  
Vol 22 (11) ◽  
pp. 3323-3357 ◽  
Author(s):  
Ronald A. Farrar-Tobar ◽  
Andrea Dell'Acqua ◽  
Sergey Tin ◽  
Johannes G. de Vries
Keyword(s):  
Carbonyl Compounds ◽  
State Of The Art ◽  
The State ◽  
Transfer Hydrogenation ◽  
Allylic Alcohols ◽  
Selective Transfer ◽  
Unsaturated Aldehydes ◽  
Aldehydes And Ketones ◽  
Metal Catalyzed

This review describes the state-of-the-art of metal-catalyzed selective transfer hydrogenation of α,β-unsaturated aldehydes and ketones to the allylic alcohols, covering the literature of the last 30 years.

Mechanistic insights into asymmetric transfer hydrogenation of pyruvic acid catalysed by chiral osmium complexes with formic acid assisted proton transfer

2019 ◽  
Vol 55 (65) ◽  
pp. 9633-9636 ◽  
Author(s):  
Wan Wang ◽  
Xinzheng Yang
Keyword(s):  
Density Functional Theory ◽  
Formic Acid ◽  
Pyruvic Acid ◽  
Density Functional ◽  
Density Functional Theory Calculations ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Functional Theory ◽  
Osmium Complexes ◽  
Acid Catalyzed

Density functional theory calculations reveal a proton-coupled hydride transfer mechanism with the participation of formic acid for asymmetric transfer hydrogenation of pyruvic acid catalyzed by chiral Os complexes.

scholarly journals Dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid catalyzed by molybdenum hydride compounds

2015 ◽  
Vol 6 (3) ◽  
pp. 1859-1865 ◽  
Author(s):  
Michelle C. Neary ◽  
Gerard Parkin
Keyword(s):  
Formic Acid ◽  
Transfer Hydrogenation ◽  
Aldehydes And Ketones ◽  
Hydrogenation Reactions ◽  
Acid Catalyzed

Cyclopentadienyl molybdenum hydride compounds are catalysts for dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid, in which the latter provides a means to reduce aldehydes and ketones.

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