Diethylzinc: A Chain-Transfer Agent in Intermolecular Radical Additions. A Parallel with Triethylborane

1999 ◽  
Vol 64 (25) ◽  
pp. 9189-9193 ◽  
Author(s):  
Michèle P. Bertrand ◽  
Laurence Feray ◽  
Robert Nouguier ◽  
P. Perfetti
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
A Chain

Branched polystyrenes from suspension “Strathclyde” polymerization using a vulcanization accelerator as a chain transfer agent

2019 ◽  
Vol 10 (7) ◽  
pp. 885-890 ◽  
Author(s):  
Haiyang Yong ◽  
Yongpeng Miao ◽  
Sigen A ◽  
Dong Quan ◽  
Alojz Ivankovic ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Three Dimensional ◽  
Chemical Properties ◽  
Branched Polymers ◽  
Chain Transfer Agent ◽  
Molecular Architecture ◽  
Physical Chemical ◽  
A Chain ◽  
Vulcanization Accelerator

Branched polymers exhibit a unique three-dimensional (3D) molecular architecture and distinctive physical/chemical properties, and thus have been applied in a wide variety of fields.

Narrow‐disperse, cross‐linked polymer microspheres by one‐step dispersion polymerization with a chain transfer agent

2019 ◽  
Vol 31 (3) ◽  
pp. 407-414
Author(s):  
Hongxin Wang ◽  
Baijun Liu ◽  
Mingyao Zhang ◽  
Shuai Du ◽  
Gaocheng Wu ◽  
...  
Keyword(s):  
Dispersion Polymerization ◽  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Polymer Microspheres ◽  
One Step ◽  
A Chain

Investigation into the mechanism of photo-mediated RAFT polymerization involving the reversible photolysis of the chain-transfer agent

2017 ◽  
Vol 8 (11) ◽  
pp. 1760-1770 ◽  
Author(s):  
Benjamin Cabannes-Boué ◽  
Qizhi Yang ◽  
Jacques Lalevée ◽  
Fabrice Morlet-Savary ◽  
Julien Poly
Keyword(s):  
Chain Transfer ◽  
Raft Polymerization ◽  
Chain Transfer Agent ◽  
Polymerization Mechanism ◽  
A Chain

A new dithiocarbamate with a N-carbazole Z group is synthesized and investigated as a chain-transfer agent (CTA) in a photo-mediated RAFT polymerization mechanism involving its partial and reversible photolysis.

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