The kinetic theory of gelling for the radical polymerization of polyfunctional, unsaturated compounds in the presence of a chain transfer agent. Estimation of the rate constants of individual reaction stages from the gel point

We present the synthesis, characterization and photolytical degradation of branched photo-responsive poly(acrylic acid) and polystyrene using free radical polymerization of acrylic acid/styrene in the presence of a newly synthesized asymmetric o-nitrobenzyl-based crosslinker and different amounts of dodecanethiol (DDT) as a chain transfer agent.

Download Full-text

ω-Iodinated poly(dimethylsiloxane) as a chain transfer agent in iodine transfer radical polymerization of vinyl acetate and dibutyl maleate: synthesis and structural characterization

Journal of Polymer Research ◽

10.1007/s10965-016-1016-3 ◽

2016 ◽

Vol 23 (6) ◽

Cited By ~ 2

Author(s):

Mojtaba Farrokhi ◽

Mahdi Abdollahi

Keyword(s):

Radical Polymerization ◽

Vinyl Acetate ◽

Structural Characterization ◽

Chain Transfer ◽

Chain Transfer Agent ◽

Iodine Transfer ◽

Dibutyl Maleate ◽

A Chain

Download Full-text

Facile photo-flow synthesis of branched poly(butyl acrylate)s

Reaction Chemistry & Engineering ◽

10.1039/c7re00013h ◽

2017 ◽

Vol 2 (4) ◽

pp. 479-486 ◽

Cited By ~ 16

Author(s):

O. Eckardt ◽

B. Wenn ◽

P. Biehl ◽

T. Junkers ◽

F. H. Schacher

Keyword(s):

Free Radical ◽

Propylene Glycol ◽

Radical Polymerization ◽

Butyl Acrylate ◽

Chain Transfer ◽

Free Radical Polymerization ◽

Chain Transfer Agent ◽

Flow Synthesis ◽

Glycol Diacrylate ◽

A Chain

We present the synthesis of branched poly(butyl acrylate)s using photo-induced free radical polymerization of (n/t)-butyl acrylate in the presence of tri(propylene glycol) diacrylate (TPGDA) as a crosslinker and varying amounts of dodecanethiol (DDT) as a chain transfer agent to prevent macroscopic gelation.

Download Full-text

Diethylzinc: A Chain-Transfer Agent in Intermolecular Radical Additions. A Parallel with Triethylborane

The Journal of Organic Chemistry ◽

10.1021/jo9912404 ◽

1999 ◽

Vol 64 (25) ◽

pp. 9189-9193 ◽

Cited By ~ 77

Author(s):

Michèle P. Bertrand ◽

Laurence Feray ◽

Robert Nouguier ◽

P. Perfetti

Keyword(s):

Chain Transfer ◽

Chain Transfer Agent ◽

A Chain

Download Full-text

Branched polystyrenes from suspension “Strathclyde” polymerization using a vulcanization accelerator as a chain transfer agent

Polymer Chemistry ◽

10.1039/c8py01639a ◽

2019 ◽

Vol 10 (7) ◽

pp. 885-890 ◽

Cited By ~ 2

Author(s):

Haiyang Yong ◽

Yongpeng Miao ◽

Sigen A ◽

Dong Quan ◽

Alojz Ivankovic ◽

...

Keyword(s):

Chain Transfer ◽

Three Dimensional ◽

Chemical Properties ◽

Branched Polymers ◽

Chain Transfer Agent ◽

Molecular Architecture ◽

Physical Chemical ◽

A Chain ◽

Vulcanization Accelerator

Branched polymers exhibit a unique three-dimensional (3D) molecular architecture and distinctive physical/chemical properties, and thus have been applied in a wide variety of fields.

Download Full-text