Interpretation of the Gas-Phase Solvent Deuterium Kinetic Isotope Effects in the SN2 Reaction Mechanism:  Comparison of Theoretical and Experimental Results in the Reaction of Microsolvated Fluoride Ions with Methyl Halides

2006 ◽  
Vol 110 (48) ◽  
pp. 13112-13121 ◽  
Author(s):  
Gustavo E. Davico
Keyword(s):  
Reaction Mechanism ◽  
Gas Phase ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Experimental Results ◽  
Fluoride Ions ◽  
Methyl Halides ◽  
Kinetic Isotope ◽  
Sn2 Reaction

Deuterium Kinetic Isotope Effects in the Gas-Phase SN2 Reactions of Solvated Fluoride Ions with Methyl Halides†

2004 ◽  
Vol 108 (45) ◽  
pp. 9887-9891 ◽  
Author(s):  
Shuji Kato ◽  
Jale Hacaloglu ◽  
Gustavo E. Davico ◽  
Charles H. DePuy ◽  
Veronica M. Bierbaum
Keyword(s):  
Gas Phase ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Fluoride Ions ◽  
Methyl Halides ◽  
Sn2 Reactions ◽  
Kinetic Isotope

Measurements of Solvent and Secondary Kinetic Isotope Effects for the Gas-Phase SN2 Reactions of Fluoride with Methyl Halides

1994 ◽  
Vol 116 (8) ◽  
pp. 3609-3610 ◽  
Author(s):  
Richard A. J. O'Hair ◽  
Gustavo E. Davico ◽  
Jale Hacaloglu ◽  
Thuy Thanh Dang ◽  
Charles H. DePuy ◽  
...  
Keyword(s):  
Gas Phase ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Methyl Halides ◽  
Sn2 Reactions ◽  
Kinetic Isotope

scholarly journals Deuterium kinetic isotope effects in microsolvated gas-phase E2 reactions

2007 ◽  
Vol 18 (6) ◽  
pp. 1046-1051 ◽  
Author(s):  
Nicole Eyet ◽  
Stephanie M. Villano ◽  
Shuji Kato ◽  
Veronica M. Bierbaum
Keyword(s):  
Gas Phase ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope
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