Effects of Reorientation in Vibrational Sum-Frequency Spectroscopy†

2007 ◽  
Vol 111 (25) ◽  
pp. 8902-8915 ◽  
Author(s):  
John T. Fourkas ◽  
Robert A. Walker ◽  
Suleyman Z. Can ◽  
Erez Gershgoren
2016 ◽  
Vol 18 (27) ◽  
pp. 18424-18430 ◽  
Author(s):  
Yujin Tong ◽  
Tobias Kampfrath ◽  
R. Kramer Campen

Vibrational sum frequency spectroscopy measurements reveal that the libration frequency of interfacial water is significantly higher than bulk liquid water, suggesting that water's rotational potential stiffens on moving from the bulk liquid to the air/water interface.


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