Hydration Energies of Sodiated Amino Acids from Gas-Phase Equilibria Determinations

2007 ◽  
Vol 111 (26) ◽  
pp. 5784-5791 ◽  
Author(s):  
Henryk Wincel

Author(s):  
Dennis Sherwood ◽  
Paul Dalby

Another key chapter, examining reactions in solution. Starting with the definition of an ideal solution, and then introducing Raoult’s law and Henry’s law, this chapter then draws on the results of Chapter 14 (gas phase equilibria) to derive the corresponding results for equilibria in an ideal solution. A unique feature of this chapter is the analysis of coupled reactions, once again using first principles to show how the coupling of an endergonic reaction to a suitable exergonic reaction results in an equilibrium mixture in which the products of the endergonic reaction are present in much higher quantity. This demonstrates how coupled reactions can cause entropy-reducing events to take place without breaking the Second Law, so setting the scene for the future chapters on applications of thermodynamics to the life sciences, especially chapter 24 on bioenergetics.





2003 ◽  
Vol 228 (2-3) ◽  
pp. 825-839 ◽  
Author(s):  
Alexei Gapeev ◽  
Robert C. Dunbar


2004 ◽  
Vol 126 (6) ◽  
pp. 1836-1842 ◽  
Author(s):  
Catherine Kapota ◽  
Joël Lemaire ◽  
Philippe Maître ◽  
Gilles Ohanessian


1999 ◽  
Vol 71 (19) ◽  
pp. 4427-4429 ◽  
Author(s):  
W. Andy Tao ◽  
Duxi Zhang ◽  
Feng Wang ◽  
Peter D. Thomas ◽  
R. Graham Cooks


Proteins ◽  
1987 ◽  
pp. 383-394
Author(s):  
J. E. Shively ◽  
D. Hawke ◽  
R. M. Kutny ◽  
B. Krieger ◽  
J. L. Glajch


1983 ◽  
Vol 15 (10) ◽  
pp. 989-993 ◽  
Author(s):  
Yat C Chan ◽  
William C Stwalley
Keyword(s):  


1983 ◽  
Vol 15 (10) ◽  
pp. 995-1000 ◽  
Author(s):  
Yat C Chan ◽  
William C Stwalley
Keyword(s):  


1968 ◽  
Vol 29 (2) ◽  
pp. 367-377 ◽  
Author(s):  
K.K. Shih ◽  
J.W. Allen ◽  
G.L. Pearson
Keyword(s):  


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