A New Method of Studying Ion Transfer at Liquid|Liquid Phase Boundaries Using a Carbon Nanotube Paste Electrode with a Redox Active Binder

2007 ◽  
Vol 111 (49) ◽  
pp. 18353-18360 ◽  
Author(s):  
Roohollah Torabi Kachoosangi ◽  
Lei Xiao ◽  
Gregory G. Wildgoose ◽  
Frank Marken ◽  
Philip C. Bulman Page ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Liquid Phase ◽  
New Method ◽  
Ion Transfer ◽  
Phase Boundaries ◽  
Redox Active ◽  
Carbon Nanotube Paste Electrode ◽  
Paste Electrode

Multivariate Optimization Strategies in the Development of an Electroanalytical Method for the Assay of Metoclopramide Using Mercury-Film-Modified Carbon Nanotube Paste Electrode

2010 ◽  
Vol 83 (11) ◽  
pp. 1364-1366 ◽  
Author(s):  
Camila Bitencourt Mendes ◽  
Felipe Nascimento Andrade ◽  
Mariana Gava Segatelli ◽  
Arnaldo César Pereira ◽  
Douglas Cardoso Dragunski ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Multivariate Optimization ◽  
Mercury Film ◽  
Carbon Nanotube Paste Electrode ◽  
Electroanalytical Method ◽  
Paste Electrode

scholarly journals Rapid Electrochemical Monitoring of Tyrosine by Poly (Riboflavin) Modified Carbon Nanotube Paste Electrode as a Sensitive Sensor and its Applications in Pharmaceutical Samples

2021 ◽  
Vol 11 (6) ◽  
pp. 14661-14672
Keyword(s):  
Carbon Nanotube ◽  
Differential Pulse ◽  
Pharmaceutical Samples ◽  
Electrocatalytic Effect ◽  
Carbon Nanotube Paste Electrode ◽  
Sensitive Sensor ◽  
Electro Oxidation ◽  
Electrochemical Monitoring ◽  
Paste Electrode

A poly(riboflavin) modified carbon nanotube paste electrode (PRFMCNTPE) is employed as a compatible and electrocatalytic sensor for the determination of Tyrosine (TYR). The analysis and assessment are carried out through differential pulse voltammetry (DPV) and Cyclic Voltammetry (CV). The surface of the intended sensor is examined through Field Emission Scanning Electron Microscopy (FE-SEM). The modified electrode shows the outstanding electrocatalytic effect for TYR with high selectivity and sensitivity as compared to carbon nanotube paste electrode (CNTPE). The electro-oxidation peak current of TYR and its concentration is found linear from 2 µM to 10 µM with a detection limit (LOD) of 0.45 µM. The developed sensor is productively applied for the determination of TYR in pharmaceutical samples like Tyrosine capsules. The adapted electrode shows good stability, excellent reproducibility, and remarkable sensitivity.

Ion transfer across liquid-liquid phase boundaries: electrochemical kinetics by Faradaic impedance

1989 ◽  
Vol 93 (25) ◽  
pp. 8204-8212 ◽  
Author(s):  
Thomas Wandlowski ◽  
Vladimir Marecek ◽  
Karel Holub ◽  
Zdenek Samec
Keyword(s):  
Liquid Phase ◽  
Electrochemical Kinetics ◽  
Ion Transfer ◽  
Phase Boundaries ◽  
Faradaic Impedance

Administering Pesticide Assays in In Vivo-Implanted Biosensors

2008 ◽  
Vol 61 (10) ◽  
pp. 826 ◽  
Author(s):  
Suw Young Ly ◽  
Young Sam Jung ◽  
Chang Hyun Lee ◽  
Bang Won Lee
Keyword(s):  
Carbon Nanotube ◽  
Stripping Voltammetry ◽  
Brain Cell ◽  
Relative Standard ◽  
Square Wave Stripping Voltammetry ◽  
Fruit Samples ◽  
Carbon Nanotube Paste Electrode ◽  
Analytical Time ◽  
Paste Electrode

An analytical pesticide assay of O-ethyl-O-4-(nitrophenyl)phenyl phosphonothioate (EPN) was carried out using the following: a carbon nanotube paste electrode, a mercury-immobilized carbon nanotube paste electrode, a glassy carbon electrode, a metal–gold electrode, and a DNA-immobilized carbon nanotube paste electrode (DPE), which is two-fold more sensitive than other sensors. The DPE was optimized using cyclic and square wave stripping voltammetry. Linear working ranges approached 5–55 mg L–1 EPN and the nano-range of 10–210 ng L–1 in a 0.1 mol L–1 NH4H2PO4 electrolyte solution, with a speedy analytical time of 30-s stripping. The detection limit was 2.57 ng L–1 (7.94 × 10–12 mol L–1), and the precision was 0.102% relative standard deviation (n = 15) at the 10.0 mg L–1 EPN spike. This indicates that the method is more sensitive than common voltammetric methods. This method was applied to fruit samples using patch- and needle-type electrodes, specifically on the skin tissues of an orange and an apple. Moreover, the implanted electrode was interfaced with a fish brain cell at the electrochemical workstation. Results showed that the aforementioned method can be used to conduct a pesticide assay in neuro-treated and non-treated cell systems.

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