Standard States and Thermochemical Kinetics in Heterogeneous Atmospheric Chemistry

2012 ◽  
Vol 116 (24) ◽  
pp. 6312-6316 ◽  
Author(s):  
D. J. Donaldson ◽  
M. Ammann ◽  
T. Bartels-Rausch ◽  
U. Pöschl

2002 ◽  
Vol 8 (2) ◽  
pp. 131-138 ◽  
Author(s):  
G.B. Pronchev ◽  
I.A. Korobeinikova ◽  
A.N. Yermakov

The application of fast-atom bombardment (FAB) mass spectrometry to solving the problems of heterogeneous atmospheric chemistry is briefly reviewed. The method is useful in studying the state of surfaces and molecules adsorbed thereon and looks appropriate in investigations of the dynamics and mechanisms of chemical reactions occurring both on a surface and in a volume of moving particulate matter suspended in a gas. It was shown that composition of atmospheric aerosols and components dissolved in atmospheric water (clouds, fogs, mists etc.) can be determined by the FAB technique. The given method, as was found in our investigations, allows the discrimination of ferrous and ferric ions. Detection limits for concentrations of H2SO4 and Fe(II / III) ions as essential components of atmospheric water determined in model experiments are established at the level of 10−6 M.



2001 ◽  
Vol 89 (11-12) ◽  
Author(s):  
M. Amman

Current techniques aiming to study heterogeneous atmospheric chemistry under realistic conditions are often subject to restrictions caused by the low amount of processed material, the complex composition of gas and condensed phases and interference issues. The use of the short-lived tracer



Author(s):  
C. E. Kolb ◽  
Douglas R. Worsnop ◽  
M. S. Zahniser ◽  
W. J. De Bruyn ◽  
Jeffrey A. Shorter ◽  
...  




1983 ◽  
Vol 17 (5) ◽  
pp. 1039
Author(s):  
James P. Lodge


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