DFT and Experimental Study of the Host–Guest Interactions Effect on the Structure, Properties, and Electro-Catalytic Activities of N2O2–Ni(II) Schiff-Base Complexes Incorporated into Zeolite

2012 ◽  
Vol 116 (34) ◽  
pp. 18518-18532 ◽  
Author(s):  
M. Jafarian ◽  
M. Rashvand avei ◽  
M. Khakali ◽  
F. Gobal ◽  
S. Rayati ◽  
...  
2019 ◽  
Vol 8 (4) ◽  
pp. 675-681

Metal complexes synthesized from Schiff bases and furthermore Schiff bases are versatile in nature. Such types of compounds were prepared from the condensation of an amino compound with carbonyl compounds (aldehyde or ketone) during which the carbonyl group is replaced by an imine or azomethine group. Schiff bases and their derivatives are widely employed in industries, polymers, dyes and medicative and pharmaceutical fields and additionally exhibit biological activities like antibacterial, antifungal, anti-inflammatory, antimalarial, antiviral, and antipyretic properties. Many Schiff base metal complexes exhibit glorious catalytic activities in numerous mechanisms. Their several applications in homogenous and heterogeneous catalysis were according troughout last decade. Several Schiff base complexes were helpful for their application as catalysts in reactions involving at high temperatures because of the high thermal and moisture stabilities. This text totally based on literature review with examples of the most promising applied Schiff bases and their complexes in several areas, summarizing the applications of Schiff bases and their numerous derivatives and complexes.


2017 ◽  
Vol 41 (22) ◽  
pp. 13625-13646 ◽  
Author(s):  
Sweta Kumari ◽  
Arun Kumar Mahato ◽  
Abhishek Maurya ◽  
Vijay Kumar Singh ◽  
Neha Kesharwani ◽  
...  

Enhanced bifunctional catalytic activities are shown by monobasic tridentate Cu(ii) Schiff-base complexes.


2016 ◽  
Vol 45 (47) ◽  
pp. 18967-18976 ◽  
Author(s):  
Archana Choudhary ◽  
Bidisa Das ◽  
Saumi Ray

Square planar Ni(ii)-Schiff base complexes when encapsulated in a supercage of zeolite Y have shown altered optical and magnetic properties and catalytic activities in comparison to their corresponding free states.


2011 ◽  
Vol 340 (1-2) ◽  
pp. 53-59 ◽  
Author(s):  
Jinjin Li ◽  
Jianglin Hu ◽  
Yanlong Gu ◽  
Fuming Mei ◽  
Tao Li ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (49) ◽  
pp. 28216-28237 ◽  
Author(s):  
Kousik Ghosh ◽  
Abhisek Banerjee ◽  
Antonio Bauzá ◽  
Antonio Frontera ◽  
Shouvik Chattopadhyay

Two cobalt(iii) tetrazolato complexes have been synthesized and characterized. Noncovalent interactions have been analysed by DFT and MEP calculations and characterized using Bader's theory of AIM. Both complexes catalyze the aerial oxidation of 3,5-DTBC and OAPH.


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