Comprehensive Analysis of Gly-Leu-Gly-Gly-Lys Peptide Dication Structures and Cation-Radical Dissociations Following Electron Transfer: From Electron Attachment to Backbone Cleavage, Ion–Molecule Complexes, and Fragment Separation

2013 ◽  
Vol 118 (1) ◽  
pp. 308-324 ◽  
Author(s):  
Robert Pepin ◽  
Kenneth J. Laszlo ◽  
Bo Peng ◽  
Aleš Marek ◽  
Matthew F. Bush ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Cation Radical ◽  
Electron Attachment ◽  
Comprehensive Analysis ◽  
Backbone Cleavage ◽  
Ion Molecule Complexes

Evidence for electron transfer in reactions of thianthrene cation radical with dialkylmercurials [Erratum to document cited in CA112(21):198622b]

1990 ◽  
Vol 55 (17) ◽  
pp. 5180-5180
Author(s):  
Stanislaw Lochynski ◽  
Henry J. Shine ◽  
Miroslaw Soroka ◽  
T. Krishnan Venkatachalam
Keyword(s):  
Electron Transfer ◽  
Cation Radical

ESR and optical study of electron transfer between the NO units of an N,N'-dialkoxyurea cation radical

1989 ◽  
Vol 111 (8) ◽  
pp. 2809-2815 ◽  
Author(s):  
Stephen F. Nelsen ◽  
James A. Thompson-Colon ◽  
Menahem Kaftory
Keyword(s):  
Electron Transfer ◽  
Cation Radical ◽  
Optical Study

Properties and reactivities of nonheme iron(iv)–oxo versus iron(v)–oxo: long-range electron transfer versus hydrogen atom abstraction

2014 ◽  
Vol 16 (41) ◽  
pp. 22611-22622 ◽  
Author(s):  
Baharan Karamzadeh ◽  
Devendra Singh ◽  
Wonwoo Nam ◽  
Devesh Kumar ◽  
Sam P. de Visser
Keyword(s):  
Electron Transfer ◽  
Hydrogen Atom ◽  
Long Range ◽  
Cation Radical ◽  
Nonheme Iron ◽  
Hydrogen Atom Abstraction ◽  
Computational Studies ◽  
Radical Species ◽  
Oxo Ligand

Computational studies show that the perceived nonheme iron(v)–oxo is actually an iron(iv)–oxo ligand cation radical species.

Paramagnetic organometallic molecules. XIV. Ion-pair and steric effects in dissociative electron transfer reactions of metal cluster carbonyl radical anions

1983 ◽  
Vol 36 (3) ◽  
pp. 441 ◽  
Author(s):  
CM Kirk ◽  
BM Peake ◽  
BH Robinson ◽  
J Simpson
Keyword(s):  
Electron Transfer ◽  
Metal Cluster ◽  
Metal Carbonyl ◽  
Electron Attachment ◽  
Transfer Reactions ◽  
Organic Radical ◽  
Radical Anions ◽  
Dissociative Electron Attachment ◽  
Dissociative Electron Transfer ◽  
Electron Transfer Reactions

An investigation of electron attachment reactions of cluster metal carbonyls is presented. In general, alkyl and organometallic halides react rapidly with metal carbonyl cluster radical anions at ambient temperatures to give the neutral cluster molecule. Halide ion and alkyl or organometallic radicals are also produced, which indicate that these are dissociative electron attachment reactions analogous to those of organic radical anions. The rate of dissociative electron attachment in reactions of PhCCo3(CO)9- was found to depend on the R-X bond energy, the size of the alkyl group and the nature of the counter-ion. In particular, (Ph3P)2N+ retarded some electron transfer reactions to the extent that the bimolecular decay of PhCCo3(CO)9- effectively competed with the electron transfer process in determining the reaction path.

Multiple-Electron Transfer in a Single Step. Design and Synthesis of Highly Charged Cation-Radical Salts

2001 ◽  
Vol 3 (18) ◽  
pp. 2887-2890 ◽  
Author(s):  
Rajendra Rathore ◽  
Carrie L. Burns ◽  
Mihaela I. Deselnicu
Keyword(s):  
Electron Transfer ◽  
Cation Radical ◽  
Single Step ◽  
Design And Synthesis
Sign in / Sign up

Export Citation Format

Share Document