Effect of the Intermolecular Excitation in the Vibrational Predissociation Dynamics of van der Waals Complexes and the Implications for Control

2014 ◽  
Vol 118 (33) ◽  
pp. 6395-6406 ◽  
Author(s):  
A. García-Vela
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Vibrational Predissociation

scholarly journals Consecutive Vibrational Redistribution and Predissociation Processes in s-Tetrazine–Argon Van Der Waals Complexes

1983 ◽  
Vol 2 (3-4) ◽  
pp. 125-135 ◽  
Author(s):  
J. J. F. Ramaekers ◽  
L. B. Krijnen ◽  
H. J. Lips ◽  
J. Langelaar ◽  
R. P. H. Rettschnick
Keyword(s):  
Decay Time ◽  
Van Der Waals ◽  
Stagnation Pressure ◽  
Van Der Waals Complexes ◽  
Supersonic Expansion ◽  
Vibrational Predissociation ◽  
Out Of Plane ◽  
Spectrally Resolved ◽  
Plane Mode

s-Tetrazine argon complexes T−Arn (n = 1, 2) are formed in a supersonic expansion of argon seeded with s-tetrazine. The expansion was conducted through a nozzle of 50 or 100 μm with an argon stagnation pressure between 1 and 1.5 bar. From spectrally resolved measurements it is clear that vibrational redistribution processes as well as vibrational predissociation processes take place after SVL excitation within the complex.From rise and decay time experiments it can be concluded, that after excitation of the 6a1 complex level, the above mentioned processes are consecutive and not parallel. It appears that the out of plane mode 16a couples with the Van der Waals stretching mode. The predissociation rate of the 16a2 complex is observed to be 2.3 × 109 s−1.

Vibrational predissociation dynamics and internal rotation in aromatic van der Waals complexes

1994 ◽  
Vol 59 (4) ◽  
pp. 397-402 ◽  
Author(s):  
B. D. Gilbert ◽  
C. S. Parmenter ◽  
M. -C. Su ◽  
H. -K. Oh ◽  
Z. -Q. Zhao
Keyword(s):  
Internal Rotation ◽  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Vibrational Predissociation

Vibrational predissociation of van der Waals complexes: Quasi-classical results with Gaussian-weighted trajectories

2008 ◽  
Vol 463 (1-3) ◽  
pp. 65-71 ◽  
Author(s):  
M.L. González-Martínez ◽  
W. Arbelo-González ◽  
J. Rubayo-Soneira ◽  
L. Bonnet ◽  
J.-C. Rayez
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Vibrational Predissociation
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