scholarly journals EPR Line Shifts and Line Shape Changes due to Spin Exchange of Nitroxide Free Radicals in Liquids: 6. Separating Line Broadening due to Spin Exchange and Dipolar Interactions

2009 ◽  
Vol 113 (17) ◽  
pp. 4930-4940 ◽  
Author(s):  
Barney L. Bales ◽  
Michelle Meyer ◽  
Steve Smith ◽  
Miroslav Peric
Keyword(s):  
Free Radicals ◽  
Line Shape ◽  
Spin Exchange ◽  
Dipolar Interactions ◽  
Line Broadening ◽  
Shape Changes

Critical Raman line shape behavior of fluid nitrogen

2004 ◽  
Vol 76 (1) ◽  
pp. 147-155 ◽  
Author(s):  
M. Musso ◽  
F. Matthai ◽  
D. Keutel ◽  
K.-L. Oehme
Keyword(s):  
Raman Line ◽  
Line Shape ◽  
Line Broadening ◽  
Vibrational Resonance ◽  
Critical Isochore ◽  
Molecular Fluids ◽  
Detection Techniques ◽  
Gas Phases ◽  
Line Shapes ◽  
Band Position

Isotropic Raman line shapes of simple molecular fluids exhibit critical line broadening near their respective liquid-gas critical points. In order to observe this phenomenon, it is essential that the band position of a given vibrational mode is density-dependent, and that vibrational depopulation processes negligibly contribute to line broadening. Special attention was given to the fact that the isotropic (i.e., nonrotationally broadened) line shape of liquid N2 is affected by resonant intermolecular vibrational interactions between identical oscillators. By means of the well-chosen isotopic mixture (14N2).975 - (14N15N).025, the temperature and density dependences of shift, width, and asymmetry of the resonantly coupled 14N2 and, depending on the S/N ratio available, of the resonantly uncoupled 14N15N were determined, with up to milli-Kelvin resolution, in the coexisting liquid and gas phases and along the critical isochore, using a highest-resolution double monochromator and modern charge-coupled device detection techniques. Clear evidence was found that vibrational resonance couplings are present in all dense phases studied.

scholarly journals Zodiacal Light - Scattered Fraunhofer Line Profiles

1996 ◽  
Vol 150 ◽  
pp. 337-340
Author(s):  
David Clarke
Keyword(s):  
Line Shape ◽  
Brightness Variation ◽  
Line Profiles ◽  
Scattering Function ◽  
Zodiacal Light ◽  
Successful Model ◽  
Fraunhofer Line ◽  
Shape Changes

AbstractThe scattering function of Hong's successful model for the brightness variation with elongation, B(ε), of the Zodiacal Light has been used to calculate profiles of Doppler shifted Fraunhofer lines. Substantial line shape changes with ε are predicted with an indication of a bifurcation at ε < 30°, so offering an explanation for reported F corona observations.

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