Structure and Bonding of Ordered Organic Monolayers of 1,3,5,7-Cyclooctatetraene on the Si(001) Surface:  Surface Cycloaddition Chemistry of an Antiaromatic Molecule

1998 ◽  
Vol 102 (4) ◽  
pp. 687-692 ◽  
Author(s):  
Jennifer S. Hovis ◽  
Robert J. Hamers
Keyword(s):  
Organic Monolayers ◽  
Structure And Bonding ◽  
Antiaromatic Molecule

Structure and Bonding of Ordered Organic Monolayers of 1,5-Cyclooctadiene on the Silicon(001) Surface

1997 ◽  
Vol 101 (46) ◽  
pp. 9581-9585 ◽  
Author(s):  
Jennifer S. Hovis ◽  
Robert J. Hamers
Keyword(s):  
Organic Monolayers ◽  
Structure And Bonding

Structure and Bonding

2007 ◽  
Keyword(s):  
Structure And Bonding

STRUCTURE AND BONDING NATURE OF Pd-Si AMORPHOUS ALLOYS

1979 ◽  
Vol 40 (C2) ◽  
pp. C2-104-C2-106
Author(s):  
A. Matsuzaki ◽  
S. Nanao ◽  
H. Ino
Keyword(s):  
Amorphous Alloys ◽  
Structure And Bonding

Thermally-Induced Dehydrogenative Coupling of Organosilanes and H-Terminated Silicon Quantum Dots onto Germanane Surfaces

2020 ◽  
Author(s):  
Haoyang Yu ◽  
Alyxandra Thiessen ◽  
Md Asjad Hossain ◽  
Marc Julian Kloberg ◽  
Bernhard Rieger ◽  
...  
Keyword(s):  
2D Materials ◽  
Future Generation ◽  
Optical Devices ◽  
Surface Reactivity ◽  
Organic Monolayers ◽  
Present Contribution ◽  
Thermally Induced ◽  
Dehydrogenative Coupling ◽  
Silicon Quantum Dot ◽  
Covalently Bonded

<div><div><div><p>Covalently bonded organic monolayers play important roles in defining the solution processability, ambient stability, and electronic properties of two-dimensional (2D) materials such as Ge nanosheets (GeNSs); they also hold promise of providing avenues for the fabrication of future generation electronic and optical devices. Functionalization of GeNS normally involves surface moieties linked through covalent Ge−C bonds. In the present contribution we extend the scope of surface linkages to include Si−Ge bonding and present the first demonstration of heteronuclear dehydrocoupling of organosilanes to hydride-terminated GeNSs obtained from the deintercalation and exfoliation of CaGe2. We further exploit this new surface reactivity and demonstrated the preparation of directly bonded silicon quantum dot-Ge nanosheet hybrids.</p></div></div></div>

ESR study of the structure and bonding situation in thiocyanatocopper(II) complexes with imidazole derivatives

1988 ◽  
Vol 53 (1) ◽  
pp. 56-60
Author(s):  
Anna Mašlejová ◽  
Reinhard Kirmse
Keyword(s):  
Unpaired Electron ◽  
Hyperfine Splitting ◽  
Esr Spectra ◽  
Ligand Field ◽  
Imidazole Derivatives ◽  
Bonding Parameters ◽  
Monomeric Complex ◽  
Structure And Bonding ◽  
Frozen Solutions ◽  
Planar Symmetry

ESR spectra of thianatocopper(II) complexes with imidazole derivatives were studied in ethanolic solutions at 295 and 123 K. Axialsymmetric spectra, attributed to the monomeric complex units, were obtained for the frozen solutions. The bonding parameters were interpreted by using calculated g, Cu-hyperfine, and 14N-ligand hyperfine splitting values. The Cu-N bond parameters indicate a considerable delocalization of the unpaired electron. The values of the isotropic Cu-hyperfine splitting suggest that the deviations from the planar symmetry of the CuN4 units are due to tetrahedral perturbation of the ligand field.

scholarly journals Multiple electrochemically accessible colour states in surface-confined metal-organic monolayers: Stepwise embedding individual metal centres

2021 ◽  
Author(s):  
Nadia O. Laschuk ◽  
Rana Ahmad ◽  
Iraklii I. Ebralidze ◽  
Jade Poisson ◽  
Franco Gaspari ◽  
...  
Keyword(s):  
Iron Complexes ◽  
Organic Monolayers ◽  
Individual Metal ◽  
Surface Enhanced ◽  
Metal Organic

Sequential covalent embedding of cobalt, osmium, and iron complexes of 4'-(pyridin-4-yl)-2,2':6',2''-terpyridine to surface-enhanced support pre-functionalized with a templating layer results in hetero-bimetallic (Os-Fe and Co-Fe) and hetero-trimetallic (Co-Os-Fe) monolayer materials....

Synthesis, Structure, and Bonding of Lu7Z2Te2(Z = Ni, Pd, Ru). Linking Typical Tricapped Trigonal Prisms in Metal-Rich Compounds

2004 ◽  
Vol 43 (11) ◽  
pp. 3371-3376 ◽  
Author(s):  
Ling Chen ◽  
John D. Corbett
Keyword(s):  
Structure And Bonding ◽  
Trigonal Prisms

Magnetic structure and bonding of rare-earth diboride compounds R B2 : First-principles calculations

2012 ◽  
Vol 249 (7) ◽  
pp. 1470-1476 ◽  
Author(s):  
S. Kacimi ◽  
B. Bekkouche ◽  
A. Boukortt ◽  
F. Zazoua ◽  
M. Djermouni ◽  
...  
Keyword(s):  
Rare Earth ◽  
Magnetic Structure ◽  
First Principles ◽  
First Principles Calculations ◽  
Structure And Bonding
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