Self-Assembly of Ionic Liquid (BMI-PF6)-Stabilized Gold Nanoparticles on a Silicon Surface: Chemical and Structural Aspects

Langmuir ◽  
2008 ◽  
Vol 24 (15) ◽  
pp. 7785-7792 ◽  
Author(s):  
Om P. Khatri ◽  
Kosaku Adachi ◽  
Kuniaki Murase ◽  
Ken-ichi Okazaki ◽  
Tsukasa Torimoto ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Ionic Liquid ◽  
Self Assembly ◽  
Silicon Surface ◽  
Surface Chemical ◽  
Structural Aspects

Temperature and anion responsive self-assembly of ionic liquid block copolymers coating gold nanoparticles

2016 ◽  
Vol 10 (2) ◽  
pp. 178-186 ◽  
Author(s):  
Junbo Li ◽  
Jianlong Zhao ◽  
Wenlan Wu ◽  
Ju Liang ◽  
Jinwu Guo ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Ionic Liquid ◽  
Block Copolymers ◽  
Self Assembly

scholarly journals Crystallographic insights into the structural aspects of thioctic acid based halogen-bond donor for the functionalization of gold nanoparticles

2017 ◽  
Vol 73 (2) ◽  
pp. 240-246 ◽  
Author(s):  
Kavitha Buntara Sanjeeva ◽  
Ilaria Tirotta ◽  
Vijith Kumar ◽  
Francesca Baldelli Bombelli ◽  
Giancarlo Terraneo ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Gold Nanoparticles ◽  
Self Assembly ◽  
Halogen Bond ◽  
Halogen Bonding ◽  
Thioctic Acid ◽  
Halogen Bonds ◽  
Donor Ligand ◽  
Structural Aspects

The synthesis and self-assembly capabilities of a new halogen-bond donor ligand, 2,3,5,6-tetrafluoro-4-iodophenyl 5-(1,2-dithiolan-3-yl)pentanoate (1), are reported. The crystal structure of ligand (1) and the formation of a cocrystal with 1,2-di(4-pyridyl)ethylene, (1)·(2), both show halogen bonds involving the 4-iodotetrafluorobenzene moiety. Ligand (1), being a self-complementary unit, forms an infinite halogen-bonded chain driven by the S...I synthon, while the cocrystal (1)·(2) self-assembles into a discrete trimeric entity driven by the N...I synthon. Ligand (1) was also successfully used to functionalize the surface of gold nanoparticles, AuNP-(1). Experiments on the dispersibility profile of AuNP-(1) demonstrated the potential of halogen bonding in facilitating the dispersion of modified NPs with halogen-bond donors in pyridine.

Plasmon switching of gold nanoparticles through thermo-responsive terminal breathing of surface-grafted DNA in hydrated ionic liquid

The Analyst ◽  
2021 ◽  
Author(s):  
Lu Cheng ◽  
Luyang Wang ◽  
zhiyu He ◽  
Xun Sun ◽  
Yujin Li ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Self Assembly ◽  
Optoelectronic Devices ◽  
Building Blocks ◽  
The Rich

Self-assembly performed in ionic liquids (ILs) as a unique solvent promises distinct functions and applications in sensors, therapeutics, and optoelectronic devices, due to the rich interactions between nanoparticle building blocks...

Directed Self-Assembly of Gold Nanoparticles on Graphene-Ionic Liquid Hybrid for Enhancing Electrocatalytic Activity

2011 ◽  
Vol 23 (4) ◽  
pp. 850-857 ◽  
Author(s):  
Min Ho Yang ◽  
Bong Gill Choi ◽  
HoSeok Park ◽  
Tae Jung Park ◽  
Won Hi Hong ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Ionic Liquid ◽  
Self Assembly ◽  
Electrocatalytic Activity

Preparation of Gold Nanoparticles Deposited Silicon Thin Film Electrode by Self-Assembly Method for the Employment of an Anode Material for Lithium Secondary Batteries

2015 ◽  
Vol 15 (10) ◽  
pp. 8222-8227 ◽  
Author(s):  
Martin Halim ◽  
Jung Sub Kim ◽  
Si Hieu Nguyen ◽  
Bup Ju Jeon ◽  
Joong Kee Lee
Keyword(s):  
Thin Films ◽  
Gold Nanoparticles ◽  
Anode Material ◽  
Self Assembly ◽  
Silicon Surface ◽  
Sodium Citrate ◽  
Reversible Capacity ◽  
Lithium Secondary Batteries ◽  
Silicon Thin Films ◽  
Assembly Method

This work describes a self-assembly method of gold nanoparticles coating on the surface of silicon thin films for the anode material of lithium secondary batteries. The preparation of the silicon thin films was carried out by electron cyclotron resonance metal organic chemical vapor deposition (ECR-MOCVD) process. The obtained films were further coated with (3-aminopropyl)-trimethoxysilane (APTMS) which has a role to bind the oxygen functional groups on Si surface and the gold nanoparticles. The dispersed gold nanoparticles on the surface of silicon thin films could be prepared due to self-assembly phenomena which interact between attraction and repulsion in gold nanoparticles colloidal solution (GNCS). The use of reducing agent of sodium citrate and tannic acid in GNCS significantly affected the size of gold nanoparticle in our experimental range. Based on our experimental results, the higher reversible capacity was exhibited for the silicon that was immersed in the GNCS consisted of only sodium citrate. The GNCS consisted of both sodium citrate and tannic acid produced severe coagulated nanoparticles when deposited on the silicon surface and thus inhibited the lithium movement from electrolyte to silicon surface. Consequently, the reversible capacity of silicon anode material with coagulated gold nanoparticles coating showed the reduced performance.

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