Symmetry-Based Vibrational Analysis of Polyatomic Ionic Species in Polymer Electrolytes:  Application to the Compounds Poly(ethylene oxide)3LiCF3SO3and Poly(ethylene oxide)NaCF3SO3

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Cell failure of polymer electrolytes is rather the result of short circuits instead of assumed electrolyte oxidation. A spacer with a constant and defined distance can avoid this failure, thus realize a benchmark system for a more systematic R&D.



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