One-Pot Synthesis of Star Polymers by Living Radical Polymerization

2003 ◽  
Vol 36 (8) ◽  
pp. 2990-2993 ◽  
Author(s):  
Koji Ishizu ◽  
Jaebum Park ◽  
Takeshi Shibuya ◽  
Atsushi Sogabe
Keyword(s):  
Radical Polymerization ◽  
Star Polymers ◽  
Living Radical Polymerization ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26049-26055
Author(s):  
Tam Thi-Thanh Huynh ◽  
Si Eun Kim ◽  
Soon Cheon Kim ◽  
Jin Chul Kim ◽  
Young Il Park ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
One Pot ◽  
Gradient Copolymers ◽  
One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

One-pot synthesis of optically active polymervia concurrent cooperation of enzymatic resolution and living radical polymerization

2013 ◽  
Vol 4 (2) ◽  
pp. 264-267 ◽  
Author(s):  
Changkui Fu ◽  
Chongyu Zhu ◽  
Shiqi Wang ◽  
Honglei Liu ◽  
Yun Zhang ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Optically Active ◽  
One Pot ◽  
Enzymatic Resolution ◽  
One Pot Synthesis

Fe(0) powder-catalyzed one-pot reaction: concurrent living radical polymerization and click chemistry for topological polymers

2015 ◽  
Vol 6 (26) ◽  
pp. 4794-4800 ◽  
Author(s):  
Hui Zhu ◽  
Gaojian Chen ◽  
Zhenbiao Zhang ◽  
Nianchen Zhou ◽  
Weidong Zhang ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Click Chemistry ◽  
Radical Polymerization ◽  
Star Polymers ◽  
Living Radical Polymerization ◽  
One Pot

Fe(0) powder-catalyzed one-pot reaction was successfully employed to design linear and star polymers in a well-controlled manner by combining ambient temperature living radical polymerization and click chemistry.

scholarly journals One-Pot Synthesis of Block Copolymers by a Combination of Living Cationic and Controlled Radical Polymerization

2019 ◽  
Vol 40 (1) ◽  
pp. 1970001
Author(s):  
Anne-Kristin Trützschler ◽  
Meike N. Leiske ◽  
Maria Strumpf ◽  
Johannes C. Brendel ◽  
Ulrich S. Schubert
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals One-pot synthesis of biomimetic glutathione peroxidase with temperature responsive catalytic behaviors

RSC Advances ◽  
2019 ◽  
Vol 9 (49) ◽  
pp. 28814-28822
Author(s):  
Shufei Jiao ◽  
Ruirui Zhang ◽  
Yanzhen Yin ◽  
Shuming Zhong ◽  
Zijie Liu ◽  
...  
Keyword(s):  
Glutathione Peroxidase ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
One Pot ◽  
Catalytic Behavior ◽  
Temperature Responsive ◽  
One Pot Synthesis

A microgel-based biomimetic glutathione peroxidase with temperature responsive catalytic behavior is synthesized by integrating atom transfer radical polymerization (ATRP) technology into one-pot synthesis.

Star Polymers of Sodium Styrenesulfonate Prepared by One-Pot TEMPO-Controlled SFRP

2012 ◽  
Vol 65 (8) ◽  
pp. 1117 ◽  
Author(s):  
Jianfu Ding ◽  
Steven Holdcroft
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Radical Polymerization ◽  
Star Polymers ◽  
One Pot ◽  
Stable Free Radical ◽  
Radical Coupling ◽  
Repeat Units ◽  
Divinyl Benzene ◽  
Sodium Styrenesulfonate

Star polymers of sodium styrenesulfonate with controlled arm length were prepared in a one-pot polymerization. Sodium styrenesulfonate was first polymerized with controlled molecular weight and narrow polydispersity by stable free radical polymerization. Poly(sodium styrenesulfonate) was terminated with divinyl benzene and star polymers prepared via stable free radical coupling of vinylic terminal groups. Star polymers based on arms of 20 and 32 repeat units possessed ~33 and ~41 arms per star respectively. Formation of star polymers with much longer arms was limited by poor coupling kinetics.

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