Synthesis of Star Block Copolymers from Dendrimer Initiators by Combining Ring-Opening Polymerization and Atom Transfer Radical Polymerization

2004 ◽  
Vol 37 (24) ◽  
pp. 8854-8862 ◽  
Author(s):  
Zhao ◽  
Shuai ◽  
Chen ◽  
Fu Xi
Keyword(s):  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Atom Transfer ◽  
Star Block Copolymers

Block copolymer synthesis in one shot: concurrent metal-free ATRP and ROP processes under sunlight

2017 ◽  
Vol 8 (19) ◽  
pp. 2899-2903 ◽  
Author(s):  
Cansu Aydogan ◽  
Ceren Kutahya ◽  
Andrit Allushi ◽  
Gorkem Yilmaz ◽  
Yusuf Yagci
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Atom Transfer ◽  
Metal Free

A completely metal-free strategy was developed by combining Atom Transfer Radical Polymerization (ATRP) and Ring Opening Polymerization (ROP) for the syntheses of block copolymers.

Synthesis of PCL-PS Star-Block Copolymer by Combination of Lipase-Catalyzed Ring-Opening Polymerization and ATRP

2006 ◽  
Vol 11-12 ◽  
pp. 749-752 ◽  
Author(s):  
Rui Xue Liu ◽  
Yan Shi ◽  
Zhi Feng Fu
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
1H Nmr ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Star Block Copolymer ◽  
Star Block Copolymers

Poly(ε-caprolactone) (PCL)-polystyrene (PS)star-block copolymer with a cross-linked microgel core were synthesized by the combination of atom transfer radical polymerization (ATRP) of St and lipase-catalyzed ring-opening polymerization (ROP) of ε-CL. The characterization of PCL-Br, PCL-PS-Br macroinitiator and PCL-PS Star-block copolymers was detected by GPC and 1H NMR. Results showed that the target star-block copolymers were successfully prepared.

Cascade Synthesis of Chiral Block Copolymers Combining Lipase Catalyzed Ring Opening Polymerization and Atom Transfer Radical Polymerization

2004 ◽  
Vol 5 (5) ◽  
pp. 1862-1868 ◽  
Author(s):  
Joris Peeters ◽  
Anja R. A. Palmans ◽  
Martijn Veld ◽  
Freek Scheijen ◽  
Andreas Heise ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Atom Transfer
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