Confinement Effects on Cross-Linking within Electrostatic Layer-by-Layer Assemblies Containing Poly(allylamine hydrochloride) and Poly(acrylic acid)

2010 ◽  
Vol 43 (22) ◽  
pp. 9473-9479 ◽  
Author(s):  
Woo-Sik Jang ◽  
Anne T. Jensen ◽  
Jodie L. Lutkenhaus
Keyword(s):  
Acrylic Acid ◽  
Cross Linking ◽  
Layer By Layer ◽  
Confinement Effects ◽  
Allylamine Hydrochloride ◽  
Poly Acrylic Acid

γ-Irradiation Induced Synthesis of Titanium Dioxide/Poly(acrylic acid) (TiO2/PAA) Nanocomposites and Layer-by-Layer Assembly on Glass Substrate

2015 ◽  
Vol 1098 ◽  
pp. 25-30 ◽  
Author(s):  
Lawrence John Paulo L. Trinidad ◽  
Ken Aldren S. Usman ◽  
Leon M. Payawan
Keyword(s):  
Acrylic Acid ◽  
Layer Thickness ◽  
Titania Nanoparticles ◽  
Cross Linking ◽  
Layer By Layer ◽  
Γ Irradiation ◽  
Sem Images ◽  
Nucleation Sites ◽  
Anatase Titania ◽  
Poly Acrylic Acid

Adsorption and encapsulation of the nanoparticles in polyelectrolytes impart stability to the nanometal by preventing aggregation through electrostatic and steric effects. Poly (acrylic acid) (PAA) was employed as a polymer cap to anatase titania nanoparticles. Cross-linking of the polymer was done via free-radical cross-linking using gamma-irradiation. The size of the nanocomposite produced ranged from 40-120 nm. SEM images showed that excess TiO2 in solution becomes nucleation sites for aggregation. Film assembly of the synthesized nanocomposite were done by layer-by-layer deposition with PDDA. Films formed with increasing thickness (5, 10, and 15 layers) were analyzed under AFM and shown to have a thickness of 0.25 μm, 1.1μm and 3.0 μm respectively.The average film layer thickness obtained ranged from 50-200 nm per TiO2/PAA-PDDA layer where as the number of layers deposited increase, the layer thickness increase while the roughness decreases.

Palladium Nanoparticles Embedded in a Layer-by-Layer Nanoreactor Built with Poly(Acrylic Acid) Using “Electro-Click Chemistry”

Langmuir ◽  
2016 ◽  
Vol 32 (27) ◽  
pp. 6836-6842 ◽  
Author(s):  
Matias Villalba ◽  
Mariano Bossi ◽  
Maria del Pozo ◽  
Ernesto J. Calvo
Keyword(s):  
Acrylic Acid ◽  
Click Chemistry ◽  
Palladium Nanoparticles ◽  
Layer By Layer ◽  
Poly Acrylic Acid

Pulses of Fast Electrons as a Tool To Synthesize Poly(acrylic acid) Nanogels. Intramolecular Cross-Linking of Linear Polymer Chains in Additive-Free Aqueous Solution

2003 ◽  
Vol 36 (7) ◽  
pp. 2484-2492 ◽  
Author(s):  
Slawomir Kadlubowski ◽  
Jaroslaw Grobelny ◽  
Wielislaw Olejniczak ◽  
Michal Cichomski ◽  
Piotr Ulanski
Keyword(s):  
Aqueous Solution ◽  
Acrylic Acid ◽  
Polymer Chains ◽  
Linear Polymer ◽  
Cross Linking ◽  
Fast Electrons ◽  
Poly Acrylic Acid

Photocatalytic Nanostructured Self-Assembled Poly(allylamine hydrochloride)/Poly(acrylic acid) Polyelectrolyte Films Containing Titanium Dioxide–Gold Nanoparticles for Hydrogen Generation

2013 ◽  
Vol 117 (44) ◽  
pp. 23235-23243 ◽  
Author(s):  
Nicolle Dal’Acqua ◽  
Francine Ramos Scheffer ◽  
Rosiana Boniatti ◽  
Barbara Virgínia Mendonça da Silva ◽  
Janaina Viana de Melo ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Titanium Dioxide ◽  
Acrylic Acid ◽  
Hydrogen Generation ◽  
Allylamine Hydrochloride ◽  
Self Assembled ◽  
Poly Acrylic Acid

Antibacterial Layer‐by‐Layer Films of Poly(acrylic acid)–Gentamicin Complexes with a Combined Burst and Sustainable Release of Gentamicin

2019 ◽  
Vol 6 (22) ◽  
pp. 1901373 ◽  
Author(s):  
Ane Escobar ◽  
Nicolás E. Muzzio ◽  
Patrizia Andreozzi ◽  
Sara Libertone ◽  
Elisamaria Tasca ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Layer By Layer ◽  
Poly Acrylic Acid
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