Origin of Initial Uncontrolled Polymerization and Its Suppression in the Copper(0)-Mediated Living Radical Polymerization of Methyl Acrylate in a Nonpolar Solvent

Andrew G. West; Ben Hornby; Jessica Tom; Vincent Ladmiral; Simon Harrisson; Sébastien Perrier

doi:10.1021/ma201568h

Origin of Initial Uncontrolled Polymerization and Its Suppression in the Copper(0)-Mediated Living Radical Polymerization of Methyl Acrylate in a Nonpolar Solvent

Macromolecules ◽

10.1021/ma201568h ◽

2011 ◽

Vol 44 (20) ◽

pp. 8034-8041 ◽

Cited By ~ 29

Author(s):

Andrew G. West ◽

Ben Hornby ◽

Jessica Tom ◽

Vincent Ladmiral ◽

Simon Harrisson ◽

...

Keyword(s):

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Nonpolar Solvent

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One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽

10.1039/d1ra04595d ◽

2021 ◽

Vol 11 (42) ◽

pp. 26049-26055

Author(s):

Tam Thi-Thanh Huynh ◽

Si Eun Kim ◽

Soon Cheon Kim ◽

Jin Chul Kim ◽

Young Il Park ◽

...

Keyword(s):

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

One Pot ◽

Gradient Copolymers ◽

One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

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Polymerization of methyl acrylate mediated by copper(0)/Me6-TREN in hydrophobic media enhanced by phenols; Single electron transfer-living radical polymerization

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.23042 ◽

2008 ◽

Vol 46 (22) ◽

pp. 7376-7385 ◽

Cited By ~ 86

Author(s):

Peter M. Wright ◽

Giuseppe Mantovani ◽

David M. Haddleton

Keyword(s):

Electron Transfer ◽

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Single Electron ◽

Single Electron Transfer ◽

Hydrophobic Media

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Gradient copolymers of styrene–methyl acrylate and styrene–acrylic acid by organostibine-mediated controlled/living radical polymerization and their glass transition behaviors

Polymer Chemistry ◽

10.1039/c3py00484h ◽

2013 ◽

Vol 4 (17) ◽

pp. 4639 ◽

Cited By ~ 8

Author(s):

Jinping Zhang ◽

Jun Li ◽

Liyan Huang ◽

Zhengping Liu

Keyword(s):

Glass Transition ◽

Acrylic Acid ◽

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Gradient Copolymers ◽

Controlled Living Radical Polymerization

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Living radical polymerization of vinyl acetate and methyl acrylate mediated by Co(Salen*) complexes

Polymer Chemistry ◽

10.1039/c3py00282a ◽

2013 ◽

Vol 4 (10) ◽

pp. 3098 ◽

Cited By ~ 40

Author(s):

Chei-Ming Liao ◽

Ching-Chun Hsu ◽

Fu-Sheng Wang ◽

Bradford B. Wayland ◽

Chi-How Peng

Keyword(s):

Radical Polymerization ◽

Vinyl Acetate ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Salen Complexes

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No Reduction of CuBr2 during Cu(0)-Catalyzed Living Radical Polymerization of Methyl Acrylate in DMSO at 25 °C

Macromolecules ◽

10.1021/ma301547n ◽

2012 ◽

Vol 45 (20) ◽

pp. 8267-8274 ◽

Cited By ~ 60

Author(s):

Martin E. Levere ◽

Nga H. Nguyen ◽

Virgil Percec

Keyword(s):

Radical Polymerization ◽

Methyl Acrylate ◽

No Reduction ◽

Living Radical Polymerization

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Manganese-Based Controlled/Living Radical Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene: Highly Active, Versatile, and Photoresponsive Systems

Macromolecules ◽

10.1021/ma801151s ◽

2008 ◽

Vol 41 (20) ◽

pp. 7359-7367 ◽

Cited By ~ 102

Author(s):

Kazuhiko Koumura ◽

Kotaro Satoh ◽

Masami Kamigaito

Keyword(s):

Radical Polymerization ◽

Vinyl Acetate ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Highly Active ◽

Acetate Methyl ◽

Controlled Living Radical Polymerization

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MALDI-TOF Analysis of Halogen Telechelic Poly(methyl methacrylate)s and Poly(methyl acrylate)s Prepared by Atom Transfer Radical Polymerization (ATRP) or Single Electron Transfer-Living Radical Polymerization (SET-LRP)

Macromolecular Chemistry and Physics ◽

10.1002/macp.201500144 ◽

2015 ◽

Vol 216 (17) ◽

pp. 1791-1800 ◽

Cited By ~ 10

Author(s):

Justine Couthouis ◽

Helmut Keul ◽

Martin Möller

Keyword(s):

Electron Transfer ◽

Methyl Methacrylate ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Single Electron ◽

Atom Transfer ◽

Single Electron Transfer ◽

Maldi Tof

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Surface-Dependent Kinetics of Cu(0)-Wire-Catalyzed Single-Electron Transfer Living Radical Polymerization of Methyl Acrylate in DMSO at 25 °C

Macromolecules ◽

10.1021/ma8028562 ◽

2009 ◽

Vol 42 (7) ◽

pp. 2379-2386 ◽

Cited By ~ 206

Author(s):

Nga H. Nguyen ◽

Brad M. Rosen ◽

Gerard Lligadas ◽

Virgil Percec

Keyword(s):

Electron Transfer ◽

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Single Electron ◽

Single Electron Transfer ◽

Kinetics Of

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Improving the initiation efficiency in the single electron transfer living radical polymerization of methyl acrylate with electronic chain-end mimics

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.24543 ◽

2011 ◽

Vol 49 (5) ◽

pp. 1235-1247 ◽

Cited By ~ 51

Author(s):

Nga H. Nguyen ◽

Brad M. Rosen ◽

Virgil Percec

Keyword(s):

Electron Transfer ◽

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Single Electron ◽

Single Electron Transfer

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SYNTHESIS OF BRANCHED POLY(METHYL ACRYLATE) VIA SINGLE ELECTRON TRANSFER LIVING RADICAL POLYMERIZATION

Acta Polymerica Sinica ◽

10.3724/sp.j.1105.2012.11195 ◽

2012 ◽

Vol 012 (4) ◽

pp. 398-403

Author(s):

Yiliang ZHENG ◽

Xiaoqiang XUE ◽

Wenyan HUANG ◽

Jian ZHU ◽

Bibiao JIANG

Keyword(s):

Electron Transfer ◽

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Single Electron ◽

Single Electron Transfer

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