scholarly journals Water-Soluble Poly(phosphonate)s via Living Ring-Opening Polymerization

2014 ◽  
Vol 3 (3) ◽  
pp. 244-248 ◽  
Author(s):  
Tobias Steinbach ◽  
Sandra Ritz ◽  
Frederik R. Wurm
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Water Soluble ◽  
Soluble Poly

scholarly journals Synthesis of Water-Soluble Poly(α-hydroxy acids) from Living Ring-Opening Polymerization of O-Benzyl-l-serine Carboxyanhydrides

2012 ◽  
Vol 1 (4) ◽  
pp. 441-444 ◽  
Author(s):  
Yanbing Lu ◽  
Lichen Yin ◽  
Yanfeng Zhang ◽  
Zhonghai Zhang ◽  
Yunxiang Xu ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Water Soluble ◽  
Hydroxy Acids ◽  
Soluble Poly

Biological applications of water-soluble polypeptides with ordered secondary structures

2020 ◽  
Vol 8 (31) ◽  
pp. 6530-6547 ◽  
Author(s):  
Chenglong Ge ◽  
Huan Ye ◽  
Fan Wu ◽  
Junliang Zhu ◽  
Ziyuan Song ◽  
...  
Keyword(s):  
Ring Opening ◽  
Secondary Structures ◽  
Ring Opening Polymerization ◽  
Water Soluble ◽  
Biological Applications ◽  
Recent Advances

Herein, recent advances in the synthesis of the water-soluble polypeptides with ordered secondary structures via ring-opening polymerization of NCA/NTA and their biological applications are described.

Living Photolytic Ring-Opening Polymerization of Amino-Functionalized [1]Ferrocenophanes: Synthesis and Layer-by-Layer Self-Assembly of Well-Defined Water-Soluble Polyferrocenylsilane Polyelectrolytes

2007 ◽  
Vol 13 (33) ◽  
pp. 9372-9383 ◽  
Author(s):  
Zhuo Wang ◽  
Georgeta Masson ◽  
Frank C. Peiris ◽  
Geoffrey A. Ozin ◽  
Ian Manners
Keyword(s):  
Self Assembly ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Water Soluble ◽  
Layer By Layer

scholarly journals Dewar Heterocycles as Versatile Monomers for Ring-Opening Metathesis Polymerization

2020 ◽  
Author(s):  
Sepand Nistanaki ◽  
Hosea Nelson
Keyword(s):  
Ring Opening ◽  
Water Soluble ◽  
Ring Opening Metathesis Polymerization ◽  
Valence Isomerization ◽  
Metathesis Polymerization ◽  
Grubbs Catalysts ◽  
Amino Acid Polymers ◽  
Highly Strained ◽  
Acetylene Derivatives ◽  
Soluble Poly

We report the utility of readily available heterocycles as precursors to unique ring-opening metathesis polymerization (ROMP) monomers. Photochemical valence isomerization reactions of pyridones, dihydropyridines, and pyrones dearomatize the parent heterocycles to their highly strained Dewar isomers, which readily engage in controlled ROMP reactions using Grubbs catalysts. This strategy is used to access novel polymer backbones that contain strained β-lactam and azetidine cores, which can be further derivatized using post-polymerization chemistries. We demonstrate this through the synthesis of water-soluble β-amino acid polymers and soluble poly(acetylene) derivatives.

Carbon Nanotubes Containing Metal Nanoparticles-Graft-Hyperbranched Polyglycerols Nanocomposites

2011 ◽  
Vol 284-286 ◽  
pp. 360-364
Author(s):  
Jing Zhu ◽  
Yang Liu ◽  
Juan He ◽  
Hong Liang Wei ◽  
Hui Juan Chu
Keyword(s):  
Carbon Nanotubes ◽  
Silver Nanoparticles ◽  
Metal Nanoparticles ◽  
Potential Application ◽  
Ring Opening ◽  
Multiwall Carbon Nanotubes ◽  
Ring Opening Polymerization ◽  
Water Soluble ◽  
Multiwall Carbon

New water soluble multiwall carbon nanotubes (MWCNTs) containing silver nanoparticles-grafted-hyperbranched polyglycerols (HPG) nanocomposites were synthesized and characterized successfully. In this work, MWCNTs were opened using HNO3/H2SO4mixture and filled by metal nanoparticles such as silver nanoparticles through wet chemcial method. Then MWCNTs containing silver nanoparticles (MWCNTs(Ag)) were used as macroinitiator for ring opening polymerization of glycidol and MWCNTs(Ag)-g-HPG nanocomposites were obtained. Structure of nanocomposites was evaluated by TEM, TGA and spectroscopy methods. With the solubility of MWCNTs(Ag)-g-HPG greatly improved, the new nanocomposites exhibit potential application in biomedicine and nanomedicine.

Synthesis of water soluble and multi-responsive selenopolypeptides via ring-opening polymerization of N-carboxyanhydrides

2019 ◽  
Vol 55 (54) ◽  
pp. 7860-7863 ◽  
Author(s):  
Guangqi Wu ◽  
Chenglong Ge ◽  
Xingyi Liu ◽  
Shuo Wang ◽  
Letian Wang ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Water Soluble

Synthesis of selenopolypeptides via ring opening polymerization of N-carboxyanhydrides.

A Water-Soluble Polycarbonate With Dimethylamino Pendant Groups Prepared by Enzyme-Catalyzed Ring-Opening Polymerization

2012 ◽  
Vol 33 (8) ◽  
pp. 693-697 ◽  
Author(s):  
Xiaojin Zhang ◽  
Mengmeng Cai ◽  
Zhenlin Zhong ◽  
Renxi Zhuo
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Water Soluble

scholarly journals Dewar Heterocycles as Versatile Monomers for Ring-Opening Metathesis Polymerization

2020 ◽  
Author(s):  
Sepand Nistanaki ◽  
Hosea Nelson
Keyword(s):  
Ring Opening ◽  
Water Soluble ◽  
Ring Opening Metathesis Polymerization ◽  
Valence Isomerization ◽  
Metathesis Polymerization ◽  
Grubbs Catalysts ◽  
Amino Acid Polymers ◽  
Highly Strained ◽  
Acetylene Derivatives ◽  
Soluble Poly

We report the utility of readily available heterocycles as precursors to unique ring-opening metathesis polymerization (ROMP) monomers. Photochemical valence isomerization reactions of pyridones, dihydropyridines, and pyrones dearomatize the parent heterocycles to their highly strained Dewar isomers, which readily engage in controlled ROMP reactions using Grubbs catalysts. This strategy is used to access novel polymer backbones that contain strained β-lactam and azetidine cores, which can be further derivatized using post-polymerization chemistries. We demonstrate this through the synthesis of water-soluble β-amino acid polymers and soluble poly(acetylene) derivatives.

Porphyrin-centered Water-soluble Star-shaped Polymers: Poly(N-acetylethylenimine) and Poly(ethylenimine) Arms

1999 ◽  
Vol 03 (01) ◽  
pp. 60-64 ◽  
Author(s):  
REN-HUA JIN ◽  
KOU-ICHI MOTOYOSHI
Keyword(s):  
Fluorescence Quenching ◽  
Ring Opening ◽  
Zinc Complex ◽  
Ring Opening Polymerization ◽  
Water Soluble ◽  
H Nmr ◽  
Cationic Ring Opening Polymerization

Porphyrin-centered star-shaped polymers were synthesized through living cationic ring-opening polymerization of 2-methyl-2-oxazoline employing tetra(p-chloromethylphenyl)porphyrin (CMPP) and its zinc complex as initiators. The polymers were characterized by GPC, 1 H NMR and UV-vis and their properties were examined by fluorescence quenching.

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