Electrocatalytic Oxidative Cleavage of Electron-Deficient Substituted Stilbenes in Acetonitrile−Water Employing a New High Oxidation Potential Electrocatalyst. An Electrochemical Equivalent of Ozonolysis

2007 ◽  
Vol 9 (26) ◽  
pp. 5633-5636 ◽  
Author(s):  
Xin Wu ◽  
Anthony P. Davis ◽  
Albert J. Fry
Keyword(s):  
Oxidative Cleavage ◽  
Oxidation Potential ◽  
High Oxidation

Recent advances in the Silver catalysed synthesis of furan and its applications

2020 ◽  
Vol 09 ◽  
Author(s):  
C M A Afsina ◽  
Mohan Neetha ◽  
Thaipparambil Aneeja ◽  
Gopinathan Anilkumar
Keyword(s):  
Organic Synthesis ◽  
Oxidation Potential ◽  
Silver Complexes ◽  
Wide Spread ◽  
Silver Catalysts ◽  
Recent Advances ◽  
High Oxidation ◽  
Furan Moiety ◽  
Anti Fungal ◽  
Fragrance Compounds

: Furan and its derivatives find wide-spread application as pharmaceuticals, pigments, dyes, brighteners, flavour & fragrance compounds and insecticides. They also exhibit anti-hyperglycemic, analgesic, anti-inflammatory, antibacterial, anti-fungal and anti-tumour activities. Silver catalysts are nowadays commonly used in organic synthesis due to the high oxidation potential and versatile nature of silver complexes. In this review, we summarise the recent advances in the synthesis and applications of furan moiety using silver catalysis and covers literature from 2015-2020.

Sewage static system influence on the concentrations of nitrogen compounds in unconfined aquifers

2021 ◽  
Author(s):  
Filipe da Silva Peixoto ◽  
Itabaraci Nazareno Cavalcante
Keyword(s):  
Groundwater Quality ◽  
Total Dissolved Solids ◽  
Oxidation Potential ◽  
Nitrogen Compounds ◽  
Static System ◽  
Nitrogenous Compounds ◽  
Septic Tanks ◽  
Unconfined Aquifers ◽  
High Oxidation ◽  
Using Data

ABSTRACT This research aimed to investigate the relation between sanitary situation and groundwater quality, using the concentration of nitrogenous compounds. The aquifer studied is unconfined and situated in the periurban zone of Fortaleza (NE Brazil). Through the Geographic Information System (GIS), a relational database was created using data from the IBGE demographic census (2011), to analyze numbers of households linked to septic tanks or rudimentary cesspit. The groundwater quality was evaluated based on nitrogen compounds (N-NH3 +; NO2 -; N-NO3 -), pH, and total dissolved solids (TDS). The highest concentrations of nitrates are found in areas with a higher density of septic tanks and rudimentary cesspit. Furthermore, nitrate was more present in water table above 6.6 m, mainly in the interfluvial zones, which have a high oxidation potential. The results contribute to the loss of contamination, based on the number of households with septic tanks and rudimentary cesspit, in unconfined aquifers, which were more vulnerable to contamination, mainly in peripheric expansions areas in the cities, where the deficit in sewage services tends to be high.

scholarly journals Ultra-high oxidation potential of Ti/Cu SnO2 anodes fabricated by spray pyrolysis for wastewater treatment

2016 ◽  
Vol 683 ◽  
pp. 501-505 ◽  
Author(s):  
Aqing Chen ◽  
Xudong Zhu ◽  
Junhua Xi ◽  
Haiying Qin ◽  
Zhenguo Ji
Keyword(s):  
Wastewater Treatment ◽  
Spray Pyrolysis ◽  
Oxidation Potential ◽  
High Oxidation

Combined Ozone/HF/HCI Based Cleaning and Adjusted Emitter Etch-Back for Silicon Solar Cells

2012 ◽  
Vol 195 ◽  
pp. 305-309 ◽  
Author(s):  
Anamaria Moldovan ◽  
Katrin Birmann ◽  
Jochen Rentsch ◽  
Martin Zimmer ◽  
Thomas Gitte ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Oxidation Potential ◽  
Silicon Etching ◽  
Waste Generation ◽  
Production Lines ◽  
High Efficiency Solar Cells ◽  
High Oxidation ◽  
Cleaning Procedures ◽  
Very High

RCA cleaning in multiple variations is widely used in photovoltaic production lines for high efficiency solar cells. These commonly peroxide based cleaning procedures are effective, but suffering from large chemical consumption and waste generation. A substitution of hydrogen peroxide by ozone in cleaning solutions is not realized yet for PV devices despite its high oxidation potential and facility advantages. The very high potential of ozone cleaning has been shown in various microelectronic applications [1-7]. Dissolved ozone in HF/HCl solution gives the option of cleaning by combined silicon etching and oxidizing as well as complexing metal contaminations due to F- and Cl-.

High Oxidation Potential ≈6.0 V of Concentrated Electrolyte toward High‐Performance Dual‐Ion Battery

2021 ◽  
pp. 2100151
Author(s):  
Xiaoyu Tong ◽  
Xuewu Ou ◽  
Nanzhong Wu ◽  
Haiyan Wang ◽  
Jin Li ◽  
...  
Keyword(s):  
High Performance ◽  
Oxidation Potential ◽  
High Oxidation

scholarly journals Antimicrobial effects of high oxidation potential water on various microorganisms and an evaluation of mutagenicity of the water.

1995 ◽  
Vol 37 (2) ◽  
pp. 152-161
Author(s):  
Shojiro Asai ◽  
Masatsugu Yamamura ◽  
Mitsuhiro Noda ◽  
Ichio Takase ◽  
Kenichi Hirata ◽  
...  
Keyword(s):  
Oxidation Potential ◽  
Antimicrobial Effects ◽  
High Oxidation

scholarly journals Unlocking the Accessibility of Alkyl Radicals from Boronic Acids through Hydrogen-bond Assisted Organophotoredox Activation

2021 ◽  
Author(s):  
Prabhat Ranjan ◽  
Serena Pillitteri ◽  
Guglielmo Coppola ◽  
Monica Oliva ◽  
Erik V. Van der Eycken ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Unnatural Amino Acids ◽  
Alkyl Radical ◽  
Boronic Acids ◽  
Oxidation Potential ◽  
Radical Species ◽  
Alkyl Radicals ◽  
Hydrogen Bonding Interactions ◽  
High Oxidation ◽  
Selective Generation

Despite their prevalence in organic synthesis, the application of boronic acids (BAs) as alkyl radical precursors in visible-light assisted photocatalyzed reactions has been limited by their high oxidation potential. This study demonstrates the remarkable ability of amide solvents viz. DMA (N,N-dimethylacetamide) to participate in hydrogen-bonding interactions with BAs, thus enabling the modulation of their oxidation potential towards the generation of alkyl radicals. The developed protocol is simple, robust and demonstrates broad applicability for alkylation, allylation and elimination reactions in batch and continuous flow. The application towards dehydroalanine allows the synthesis of unnatural amino acids. Furthermore, the chemo-selective generation of radical species from BAs, in the presence of boronic ester-containing molecules, is now feasible, endorsing plausible boron-selective (bio-) orthogonal modifications.

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