Further advancements in controlling nanoscale diamond chemistry with a brominated surface intermediate

2021 ◽  
Author(s):  
Abraham Wolcott ◽  
Camron Stokes ◽  
Halim Muhammad ◽  
Jorge Lopez-Rosas ◽  
Grace Drew ◽  
...  
Keyword(s):  
Surface Intermediate

Reaction Mechanism for CCl2F2 Catalytic Decomposition over MoO3/ZrO2

2013 ◽  
Vol 295-298 ◽  
pp. 326-330 ◽  
Author(s):  
Tian Cheng Liu ◽  
Yu Jiao Guo ◽  
Ping Ning ◽  
Ming Long Yuan
Keyword(s):  
Reaction Mechanism ◽  
Main Product ◽  
Solid Acid ◽  
Fixed Bed ◽  
Catalytic Decomposition ◽  
Strong Acid ◽  
Acid Sites ◽  
Fixed Bed Reactor ◽  
Surface Intermediate ◽  
Strong Acid Sites

Catalytic hydrolysis decomposition of dichlorodifluoromethane (CCl2F2) in the presence of water vapor and oxygen was studied over a series of solid acids using a fixed-bed reactor. Solid acid MoO3/ZrO2 displayed the highest activity, over which the conversion of CCl2F2 reached 100 % at 250 °C. CO2 was the main-product and the selectivity to CClF3 remained lower than 28.0 %. CO was not detected as by-product. The decomposition activity depended on the calcination temperature and the ZrO2 content. The activity of solid acid MoO3/ZrO2 correlates well with its specific surface area and the amount of medium-strong acid sites on the surface. To explain the reaction mechanism for CCl2F2 catalytic decomposition over MoO3/ZrO2, a surface intermediate, Osurface-CF2-Osurface is proposed.

CAREM X INPRO Case Study

2004 ◽  
Author(s):  
Pablo C. Florido ◽  
Dari´o Delmastro ◽  
Daniel Brasnarof ◽  
Osvaldo E. Azpitarte
Keyword(s):  
Nuclear Reactor ◽  
Fuel Cycle ◽  
High Level Waste ◽  
Fuel Cycles ◽  
Surface Intermediate ◽  
Geological Repository ◽  
Enriched Uranium ◽  
Intermediate Storage ◽  
High Level

Argentina is performing CAREM X Nuclear System Case Study based on CAREM nuclear reactor and Once Through Fuel Cycle, using SIGMA for enriched uranium production, and a deep geological repository for final disposal of high level waste after surface intermediate storage in horizontal natural convection silos, to verify INPRO (International Project on Innovative Nuclear Reactors and Fuel Cycles) methodology. Projections show that developing countries could play a crucial role in the deployment of nuclear energy, in the next fifty years. This case study will be highly useful for checking INPRO methodology for this scenario. In this contribution to ICONE 12, the preliminary findings of the Case Study are presented, including proposals to improve the INPRO methodology.

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