Synthesis, characterization and redox properties of a new vic-dioxime and its transition metal complexes

2004 ◽  
Vol 29 (2) ◽  
pp. 180-184 ◽  
Author(s):  
Esref Tas ◽  
Mahmut Ulusoy ◽  
Mehmet Guler ◽  
Ismail Yilmaz
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Redox Properties

Übergangsmetallkomplexe instabiler Ylide, X [1] Chemische und elektrochemische Untersuchungen zu den Redox-Eigenschaften cyclischer Tetracarbonylchrom-Ylidchelatkomplexe / Transition Metal Complexes of Unstable Ylides, X [1] Chemical and Electrochemical Investigations of the Redox Properties of Cyclic Tetracarbonylchromium-Ylide-Chelate-Complexes

1987 ◽  
Vol 42 (7) ◽  
pp. 892-896 ◽  
Author(s):  
Lothar Weber ◽  
Ewald Lücke ◽  
Ulrich Kölle ◽  
S. Ohst
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
General Type ◽  
Oxidation Process ◽  
Radical Cations ◽  
Redox Properties ◽  
Chelate Complexes

Abstract Treatment of the ylide chelate complexes (CO)4 (1) with (C5H5)2Fe+PF6- leads to the organometallic radical cations 2. The oxidation process of 1 is also checked electrochemically by means of cyclovoltammetry, which exhibits a reversibel one electron oxidation between -0.1 and +0.3 V vs. SCE. These potentials are more negative than in any other complex of the general type Cr(CO)4L2 (L e.g. = PR3, CNR).

Electrochemical and theoretical study of the redox properties of transition metal complexes with {Pt2S2} cores

2004 ◽  
pp. 706-712 ◽  
Author(s):  
Rubén Mas-Ballesté ◽  
Mercé Capdevila ◽  
Pilar González-Duarte ◽  
Mohamed Hamidi ◽  
Agustí Lledós ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Study ◽  
Redox Properties

scholarly journals Structural, magnetic, redox and theoretical characterization of seven-coordinate first-row transition metal complexes with a macrocyclic ligand containing two benzimidazolyl N-pendant arms

2020 ◽  
Vol 49 (14) ◽  
pp. 4425-4440 ◽  
Author(s):  
Bohuslav Drahoš ◽  
Ivana Císařová ◽  
Oleksii Laguta ◽  
Vinicius T. Santana ◽  
Petr Neugebauer ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Calculations ◽  
Macrocyclic Ligand ◽  
Redox Properties ◽  
Theoretical Characterization ◽  
Pendant Arms

Structural, magnetic and redox properties of pentagonal bipyramidal late-first-row transition metal complexes of a benzimidazole-based macrocyclic ligand were thoroughly investigated with help of theoretical calculations.

Synthesis, characterisation and redox properties of anti-bimetallic permethylpentalene complexes

2019 ◽  
Vol 48 (13) ◽  
pp. 4263-4273
Author(s):  
Samantha C. Binding ◽  
Jennifer C. Green ◽  
Zoë R. Turner ◽  
Jean-Charles Buffet ◽  
Dermot O'Hare
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Redox Properties

Anti-bimetallic transition metal complexes based on the permethylpentanyl ligand: anti-(MCpR5)2Pn* (M = Fe, Co and Ni) have been synthesised and fully characterised.

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