Übergangsmetallkomplexe instabiler Ylide, X [1] Chemische und elektrochemische Untersuchungen zu den Redox-Eigenschaften cyclischer Tetracarbonylchrom-Ylidchelatkomplexe / Transition Metal Complexes of Unstable Ylides, X [1] Chemical and Electrochemical Investigations of the Redox Properties of Cyclic Tetracarbonylchromium-Ylide-Chelate-Complexes

1987 ◽  
Vol 42 (7) ◽  
pp. 892-896 ◽  
Author(s):  
Lothar Weber ◽  
Ewald Lücke ◽  
Ulrich Kölle ◽  
S. Ohst
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
General Type ◽  
Oxidation Process ◽  
Radical Cations ◽  
Redox Properties ◽  
Chelate Complexes

Abstract Treatment of the ylide chelate complexes (CO)4 (1) with (C5H5)2Fe+PF6- leads to the organometallic radical cations 2. The oxidation process of 1 is also checked electrochemically by means of cyclovoltammetry, which exhibits a reversibel one electron oxidation between -0.1 and +0.3 V vs. SCE. These potentials are more negative than in any other complex of the general type Cr(CO)4L2 (L e.g. = PR3, CNR).

Planare Dicarbonylrhodium(I)- und -iridium(I) -Komplexe mit polarisierbaren aromatischen Liganden / Planar Dicarbonylrhodium(I) and Iridium(I) Complexes with Polarizable Aromatic Ligands

1973 ◽  
Vol 28 (3-4) ◽  
pp. 164-167 ◽  
Author(s):  
Rolf Aderjan ◽  
Hermann Breer ◽  
Heimo J. Keller ◽  
Herbert H. Rupp
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
General Type ◽  
Analytical Data ◽  
Metal Interactions ◽  
Metal Metal ◽  
Pmr Spectra

Some new transition metal complexes of the general type M(CO)2(L-L), where M stands for Ir(I), Rh(I) and L-L for a bidentate mononegative ligand are described. They were characterized by means of analytical data and their IR and PMR spectra. The chemical and solid state properties of these compounds are related to the strength of the intermolecular metal-metal interactions.

Electrochemical and theoretical study of the redox properties of transition metal complexes with {Pt2S2} cores

2004 ◽  
pp. 706-712 ◽  
Author(s):  
Rubén Mas-Ballesté ◽  
Mercé Capdevila ◽  
Pilar González-Duarte ◽  
Mohamed Hamidi ◽  
Agustí Lledós ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Study ◽  
Redox Properties

scholarly journals Structural, magnetic, redox and theoretical characterization of seven-coordinate first-row transition metal complexes with a macrocyclic ligand containing two benzimidazolyl N-pendant arms

2020 ◽  
Vol 49 (14) ◽  
pp. 4425-4440 ◽  
Author(s):  
Bohuslav Drahoš ◽  
Ivana Císařová ◽  
Oleksii Laguta ◽  
Vinicius T. Santana ◽  
Petr Neugebauer ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Calculations ◽  
Macrocyclic Ligand ◽  
Redox Properties ◽  
Theoretical Characterization ◽  
Pendant Arms

Structural, magnetic and redox properties of pentagonal bipyramidal late-first-row transition metal complexes of a benzimidazole-based macrocyclic ligand were thoroughly investigated with help of theoretical calculations.

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