scholarly journals Nanostructuring one-dimensional and amorphous lithium peroxide for high round-trip efficiency in lithium-oxygen batteries

2018 ◽  
Vol 9 (1) ◽  
Author(s):  
Arghya Dutta ◽  
Raymond A. Wong ◽  
Woonghyeon Park ◽  
Keisuke Yamanaka ◽  
Toshiaki Ohta ◽  
...  
2015 ◽  
Vol 3 (36) ◽  
pp. 18395-18399 ◽  
Author(s):  
Wen-Bin Luo ◽  
Shu-Lei Chou ◽  
Jia-Zhao Wang ◽  
Hua-Kun Liu

B4C nanowire, a novel bifunctional electrocatalyst, is used as an electrocatalyst for Li–O2batteries, with favourable rechargeability, and high round-trip efficiency.


2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Shu-Mao Xu ◽  
Xiao Liang ◽  
Xue-Yan Wu ◽  
Shen-Long Zhao ◽  
Jun Chen ◽  
...  

AbstractInferior charge transport in insulating and bulk discharge products is one of the main factors resulting in poor cycling stability of lithium–oxygen batteries with high overpotential and large capacity decay. Here we report a two-step oxygen reduction approach by pre-depositing a potassium carbonate layer on the cathode surface in a potassium–oxygen battery to direct the growth of defective film-like discharge products in the successive cycling of lithium–oxygen batteries. The formation of defective film with improved charge transport and large contact area with a catalyst plays a critical role in the facile decomposition of discharge products and the sustained stability of the battery. Multistaged discharge constructing lithium peroxide-based heterostructure with band discontinuities and a relatively low lithium diffusion barrier may be responsible for the growth of defective film-like discharge products. This strategy offers a promising route for future development of cathode catalysts that can be used to extend the cycling life of lithium–oxygen batteries.


2014 ◽  
Vol 5 (1) ◽  
Author(s):  
Jun Lu ◽  
Lei Cheng ◽  
Kah Chun Lau ◽  
Eric Tyo ◽  
Xiangyi Luo ◽  
...  

Nano Energy ◽  
2022 ◽  
Vol 93 ◽  
pp. 106810
Author(s):  
Xudong Li ◽  
Guokang Han ◽  
Shuaifeng Lou ◽  
Zhuomin Qiang ◽  
Jiaming Zhu ◽  
...  

2015 ◽  
Vol 165 ◽  
pp. 78-84 ◽  
Author(s):  
Pengfa Li ◽  
Jiakai Zhang ◽  
Qilin Yu ◽  
Jinshuo Qiao ◽  
Zhenhua Wang ◽  
...  

2005 ◽  
Vol 3 ◽  
pp. 219-225 ◽  
Author(s):  
M. Rahman ◽  
R. Marklein

Abstract. This paper presents a time-domain technique to compute the electromagnetic fields and to reconstruct the permittivity profile within a one-dimensional medium of finite length. The medium is characterized by a permittivity as well as conductivity profile which vary only with depth. The discussed scattering problem is thus one-dimensional. The modeling tool is divided into two different schemes which are named as the forward solver and the inverse solver. The task of the forward solver is to compute the internal fields of the specimen which is performed by Green’s function approach. When a known electromagnetic wave is incident normally on the media, the resulting electromagnetic field within the media can be calculated by constructing a Green’s operator. This operator maps the incident field on either side of the medium to the field at an arbitrary observation point. It is nothing but a matrix of integral operators with kernels satisfying known partial differential equations. The reflection and transmission behavior of the medium is also determined from the boundary values of the Green's operator. The inverse solver is responsible for solving an inverse scattering problem by reconstructing the permittivity profile of the medium. Though it is possible to use several algorithms to solve this problem, the invariant embedding method, also known as the layer-stripping method, has been implemented here due to the advantage that it requires a finite time trace of reflection data. Here only one round trip of reflection data is used, where one round trip is defined by the time required by the pulse to propagate through the medium and back again. The inversion process begins by retrieving the reflection kernel from the reflected wave data by simply using a deconvolution technique. The rest of the task can easily be performed by applying a numerical approach to determine different profile parameters. Both the solvers have been found to have the ability to deal with different types of slabs and incident electromagnetic pulses. Slabs having continuous and discontinuous relative permittivity have already been tested successfully. The tested electromagnetic pulses are a Dirac, Gaussian and sinusoidal pulse. Due to sampling, the resolution of the system also plays a significant role in obtaining better outputs from this scheme.


Nano Letters ◽  
2016 ◽  
Vol 16 (3) ◽  
pp. 2076-2083 ◽  
Author(s):  
Ki Ro Yoon ◽  
Gil Yong Lee ◽  
Ji-Won Jung ◽  
Nam-Hoon Kim ◽  
Sang Ouk Kim ◽  
...  

1966 ◽  
Vol 25 ◽  
pp. 46-48 ◽  
Author(s):  
M. Lecar

“Dynamical mixing”, i.e. relaxation of a stellar phase space distribution through interaction with the mean gravitational field, is numerically investigated for a one-dimensional self-gravitating stellar gas. Qualitative results are presented in the form of a motion picture of the flow of phase points (representing homogeneous slabs of stars) in two-dimensional phase space.


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