scholarly journals Metal-organic framework and inorganic glass composites

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Louis Longley ◽  
Courtney Calahoo ◽  
René Limbach ◽  
Yang Xia ◽  
Joshua M. Tuffnell ◽  
...  

AbstractMetal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.

2020 ◽  
Author(s):  
Louis Longley ◽  
Courtney Calahoo ◽  
Rene Limbach ◽  
Joshua M. Tuffnell ◽  
Adam Sapnik ◽  
...  

<p>Metal-organic framework (MOF) glasses have become a subject of study due to their novelty as an entirely new category of melt quenched glass and their potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses, in order to fabricate a new family of optically transparent materials, composed of both MOF and inorganic glass domains. Here, we present the design rules for this family of materials, use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.</p>


2020 ◽  
Author(s):  
Louis Longley ◽  
Courtney Calahoo ◽  
Rene Limbach ◽  
Joshua M. Tuffnell ◽  
Adam Sapnik ◽  
...  

<p>Metal-organic framework (MOF) glasses have become a subject of study due to their novelty as an entirely new category of melt quenched glass and their potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses, in order to fabricate a new family of optically transparent materials, composed of both MOF and inorganic glass domains. Here, we present the design rules for this family of materials, use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.</p>


2021 ◽  
Author(s):  
Jian-Jun Liu ◽  
Jia-Jia Fu ◽  
Teng Liu ◽  
Chixian He ◽  
Feixiang Cheng

Photochromic materials coupled with the photoswitchable luminescence functionalities are of particular interest due to their potential applications in switches and optical memory devices. However, construct such materials, especially those with...


2019 ◽  
Vol 55 (60) ◽  
pp. 8705-8715 ◽  
Author(s):  
Joshua M. Tuffnell ◽  
Christopher W. Ashling ◽  
Jingwei Hou ◽  
Shichun Li ◽  
Louis Longley ◽  
...  

This Feature Article reviews a range of amorphisation mechanisms of Metal–Organic Frameworks (MOFs) and presents recent advances to produce novel MOF materials including porous MOF glasses, MOF crystal–glass composites, flux melted MOF glasses and blended zeolitic imidazolate framework glasses.


2020 ◽  
Vol 11 (36) ◽  
pp. 9910-9918
Author(s):  
Shichun Li ◽  
Shuwen Yu ◽  
Sean M. Collins ◽  
Duncan N. Johnstone ◽  
Christopher W. Ashling ◽  
...  

A lower temperature route to metal–organic framework crystal–glass composites is presented. Specifically, the annealing pre-formed ZIF-62 glass with a crystalline MOF above Tg will enable formation of a greatly expanded range of materials.


2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Jingwei Hou ◽  
Christopher W. Ashling ◽  
Sean M. Collins ◽  
Andraž Krajnc ◽  
Chao Zhou ◽  
...  

Author(s):  
Lauren N. McHugh ◽  
Michael F. Thorne ◽  
Georgina Robertson ◽  
Giorgio Divitini ◽  
Thomas D. Bennett

2021 ◽  
Vol 9 (13) ◽  
pp. 8386-8393
Author(s):  
Christopher W. Ashling ◽  
Lauren K. Macreadie ◽  
Thomas J. F. Southern ◽  
Yiming Zhang ◽  
Lauren N. McHugh ◽  
...  

MOF crystal-glass composites (MOF CGCs) are materials with crystalline MOFs embedded within a MOF glass. Here we develop two novel MOF CGCs, and explore the gas uptake and guest-size limitations within these materials.


2020 ◽  
Vol 8 (7) ◽  
pp. 3803-3813 ◽  
Author(s):  
Zijian Dai ◽  
Dennis T. Lee ◽  
Kaihang Shi ◽  
Siyao Wang ◽  
Heather F. Barton ◽  
...  

Freestanding MOF predominant hollow fiber mats are fabricated via an oxide-to-MOF conversion approach. The unique hollow fiber mats show promising potential in CO2 adsorption, CO2/N2 separation, and VOC abatement applications.


Sign in / Sign up

Export Citation Format

Share Document