Chapter 2. Nanoalloy Electrocatalysts for Alcohol Oxidation Reactions

2012 ◽  
pp. 71-96
Author(s):  
Jun Yin ◽  
Bridgid Wanjala ◽  
Bin Fang ◽  
Jin Luo ◽  
Rameshowri Loukrakpam ◽  
...  
Keyword(s):  
Alcohol Oxidation ◽  
Oxidation Reactions

Mesoporous Silica Nanoparticles Supported Atomically Precise Palladium Nanoclusters Catalyzed Aerobic Oxidation of Alcohols in Water

2021 ◽  
Vol 43 (2) ◽  
pp. 193-193
Author(s):  
Taiping Gao Taiping Gao ◽  
Xiaolin Ma Xiaolin Ma ◽  
Xin Li Xin Li ◽  
Qiang Xu and Yubao Wang Qiang Xu and Yubao Wang
Keyword(s):  
Mesoporous Silica ◽  
Silica Nanoparticles ◽  
Mesoporous Silica Nanoparticles ◽  
Aerobic Oxidation ◽  
Alcohol Oxidation ◽  
High Yield ◽  
Impregnation Method ◽  
Oxidation Reactions ◽  
Clean System ◽  
Aqueous Conditions

The first mesoporous silica nanoparticles (MSNs) supported atomically precise palladium nanoclusters catalyzed alcohol oxidation reactions in water have been achieved. The catalysts was synthesized with simple impregnation method and well characterized by TEM, FT-IR, XPS anddiffuse reflectance optical spectrum and the results proved that the Pd nanoclustersimmobilized into the pores of MSNs.The as-prepared catalyst show excellent activity for the alcohol oxidation reactions with high yield under extremely mild aqueous conditions utilizes 1 atmosphere of molecular oxygen as sole oxidant. The features of clean system, gram-scale oxidation and easy recovery catalyst make this method cost effectively and environmentally benign.

A facile approach to constructing Pd@PCN–Se nano-composite catalysts for selective alcohol oxidation reactions

2019 ◽  
Vol 7 (18) ◽  
pp. 10918-10923 ◽  
Author(s):  
Kuanhong Cao ◽  
Xin Deng ◽  
Tian Chen ◽  
Qitao Zhang ◽  
Lei Yu
Keyword(s):  
Surface Area ◽  
Oxidation Reaction ◽  
Carbon Nitride ◽  
Alcohol Oxidation ◽  
Pd Nanoparticles ◽  
Oxidation Reactions ◽  
Structure Directing Agent ◽  
Nano Composite ◽  
Composite Catalysts ◽  
Polymeric Carbon

By using Se as structure-directing agent, the surface area and total mesoporous volume of polymeric carbon nitride (PCN) could be obviously enhanced. The PCN-Se material was a better support for Pd nanoparticles, which could catalyze the alcohol oxidation reaction with broad substrate scope.

Electrochemically Regenerable Hydrogen Atom Acceptors: Mediators in Electrocatalytic Alcohol Oxidation Reactions

ACS Catalysis ◽  
2020 ◽  
Vol 10 (19) ◽  
pp. 11654-11662 ◽  
Author(s):  
Elizabeth A. McLoughlin ◽  
Keith C. Armstrong ◽  
Robert M. Waymouth
Keyword(s):  
Hydrogen Atom ◽  
Alcohol Oxidation ◽  
Oxidation Reactions

Effect of oxygen functionalisation on the electrochemical behaviour of multiwall carbon nanotubes for alcohol oxidation reactions

RSC Advances ◽  
2016 ◽  
Vol 6 (82) ◽  
pp. 78403-78408 ◽  
Author(s):  
Bryan H. R. Suryanto ◽  
Chuan Zhao
Keyword(s):  
Carbon Nanotubes ◽  
Oxidation Process ◽  
Electrochemical Behaviour ◽  
Multiwall Carbon Nanotubes ◽  
Surface Oxidation ◽  
Alcohol Oxidation ◽  
Oxidation Reactions ◽  
Oxidation Of Alcohols ◽  
Effect Of Oxygen ◽  
Multiwall Carbon

Enhanced electrocatalytic oxidation of alcohols observed at multiwall carbon nanotubes following simple surface oxidation process.

Donor functionalized ruthenium N-heterocyclic carbene complexes in alcohol oxidation reactions

2014 ◽  
Vol 43 (14) ◽  
pp. 5335-5342 ◽  
Author(s):  
Abbas Raja Naziruddin ◽  
Chun-Shiuan Zhuang ◽  
Wan-Jung Lin ◽  
Wen-Shu Hwang
Keyword(s):  
Alcohol Oxidation ◽  
Oxidation Reactions ◽  
Carbene Complexes ◽  
Coordination Modes ◽  
Pincer Complex ◽  
Oxidation Of Alcohols

Ruthenium chelates bearing N^C^O-donors in bidentate or pincer coordination modes have been prepared. The ruthenium pincer complex catalyses the oxidation of alcohols to the corresponding aldehydes with yields as high as 99%.

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