Transition-metal derivatives of the functionalized cyclopentadienyl ligand. XVI. Synthesis of the bridged complexes [(μ-η5-C5H4PPh2)M(CO)2]2 (M=Cr, Mo, W). X-Ray crystal structure of the dihydride derivative [(μ-η5-C5H4PPh2)W(CO)2H]2

1998 ◽  
Vol 22 (1) ◽  
pp. 15-23 ◽  
Author(s):  
Brigitte Brumas-Soula ◽  
Françoise Dahan ◽  
and Rene´ Poilblanc
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
X Ray ◽  
Cyclopentadienyl Ligand ◽  
Metal Derivatives ◽  
Derivatives Of

Transition-Metal Derivatives of a Functionalized Cyclopentadienyl Ligand. 15.†Synthesis and Structures of Amino Cyclopentadienyl Derivatives of Rhodium(I) and Rhodium(III) Including Water-Soluble Compounds

1997 ◽  
Vol 36 (9) ◽  
pp. 1842-1849 ◽  
Author(s):  
Athanassios I. Philippopoulos ◽  
Nick Hadjiliadis ◽  
Claire E. Hart ◽  
Bruno Donnadieu ◽  
Patrick C. Mc Gowan ◽  
...  
Keyword(s):  
Transition Metal ◽  
Water Soluble ◽  
Cyclopentadienyl Ligand ◽  
Metal Derivatives ◽  
Derivatives Of

Transition-metal derivatives of phosphinophosphazenes: x-ray crystal structures of N3P3Cl4PhPPh2, N3P3Cl4PhPPh2.cntdot.Cr(CO)5, and N3P3Cl4PhPPh2.cntdot.Ru3(CO)11

1990 ◽  
Vol 29 (3) ◽  
pp. 522-529 ◽  
Author(s):  
Harry R. Allcock ◽  
Ian Manners ◽  
Michael N. Mang ◽  
Masood Parvez
Keyword(s):  
Transition Metal ◽  
Crystal Structures ◽  
X Ray ◽  
Metal Derivatives ◽  
Derivatives Of

Synthesis and X-ray powder diffraction data of transition metal derivatives of maleic acid. I. M2+(C4H3O4−)2⋅4H2O (M2+=Mn, Fe, Co, Ni, and Zn)

2002 ◽  
Vol 17 (2) ◽  
pp. 139-143 ◽  
Author(s):  
A. Briceño ◽  
T. González ◽  
G. Díaz de Delgado ◽  
R. Guevara ◽  
J. M. Delgado
Keyword(s):  
Transition Metal ◽  
Powder Diffraction ◽  
Maleic Acid ◽  
Room Temperature ◽  
Slow Evaporation ◽  
X Ray ◽  
Metal Derivatives ◽  
Diffraction Patterns ◽  
Triclinic Unit Cell ◽  
Derivatives Of

Five transition metal derivatives of maleic acid with general formula, M2+(C4H3O4−)2⋅4H2O (M2+=Mn, Fe, Co, Ni, and Zn) were prepared by slow evaporation of the aqueous solution at room temperature. Their X-ray powder diffraction patterns were recorded and evaluated. These materials are isostructural and crystallize in a triclinic unit cell. The volume of the cells vary linearly between that of the Ni complex [V=314.65(7) Å3: a=5.1769(8) Å, b=7.317(1) Å, c=9.140(2) Å, α=108.42(2)°, β=104.61(1)°, γ=92.87(1)°] and the volume of the Mn-derivative [V=330.30(8) Å3: a=5.322(1) Å, b=7.375(1) Å, c=9.752(2) Å, α=115.48(2)°, β=106.64(2)°, γ=86.63(2)°].

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