Synthesis and properties of rhenium tricarbonyl complex bearing N-fused tetraphenylporphyrin ligand

2004 ◽  
pp. 2464 ◽  
Author(s):  
Motoki Toganoh ◽  
Tomoya Ishizuka ◽  
Hiroyuki Furuta
Keyword(s):  
Tricarbonyl Complex ◽  
Rhenium Tricarbonyl

Aptamer-Functionalized Lipid-Core Micelles Loaded with Rhenium Tricarbonyl Complex

2020 ◽  
Author(s):  
Andrea C. Ortiz ◽  
Islavo Casas ◽  
Pablo Mella ◽  
Omar Naranjo ◽  
Nancy Pizarro ◽  
...  
Keyword(s):  
Tricarbonyl Complex ◽  
Lipid Core ◽  
Rhenium Tricarbonyl

Charge separation in the non-covalent adducts of aromatic amines and the rhenium tricarbonyl complex bearing a cyclodextrin unit on a ligand

1997 ◽  
Vol 438 (1-2) ◽  
pp. 159-165 ◽  
Author(s):  
Asao Nakamura ◽  
Takashi Imai ◽  
Yuji Oda ◽  
Satoshi Okutsu ◽  
Akihiko Ueno ◽  
...  
Keyword(s):  
Charge Separation ◽  
Aromatic Amines ◽  
Tricarbonyl Complex ◽  
Covalent Adducts ◽  
Rhenium Tricarbonyl

Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex

2005 ◽  
pp. 116-117 ◽  
Author(s):  
Luciano Cuesta ◽  
Eva Hevia ◽  
Dolores Morales ◽  
Julio Pérez ◽  
Víctor Riera ◽  
...  
Keyword(s):  
Tricarbonyl Complex ◽  
Phenanthroline Ligand ◽  
Rhenium Tricarbonyl

scholarly journals Tetrathiafulvalene-based azine ligands for anion and metal cation coordination

2015 ◽  
Vol 11 ◽  
pp. 1379-1391 ◽  
Author(s):  
Awatef Ayadi ◽  
Aziz El Alamy ◽  
Olivier Alévêque ◽  
Magali Allain ◽  
Nabil Zouari ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Tricarbonyl Complex ◽  
Full Characterization ◽  
Rhenium Complex ◽  
Radical Cation Salts ◽  
Cation Coordination ◽  
Rhenium Tricarbonyl ◽  
Methyl Pyridine

The synthesis and full characterization of two tetrathiafulvalene-appended azine ligands, namely 2-([2,2’-bi(1,3-dithiolylidene)]-4-yl)-6-((2,4-dinitrophenyl)hydrazono)methyl)pyridine (L1) and 5-([2,2’-bi(1,3-dithiolylidene)]-4-yl)-2-((2,4-dinitrophenyl)hydrazono)methyl)pyridine (L2) are described. The crystal structure of ligand L1 indicates that the ligand is completely planar with the presence of a strong intramolecular N3–H3···O1 hydrogen bonding. Titration experiments with inorganic anions showed that both ligands are suitable candidates for the sensing of fluoride anions. Ligand L2 was reacted with a Re(I) cation to yield the corresponding rhenium tricarbonyl complex 3. In the crystal structure of the newly prepared electroactive rhenium complex the TTF is neutral and the rhenium cation is hexacoordinated. The electrochemical behavior of the three compounds indicates that they are promising for the construction of crystalline radical cation salts.

Aptamer-functionalized lipid-core micelles loaded with rhenium tricarbonyl complex

Polyhedron ◽  
2021 ◽  
Vol 195 ◽  
pp. 114963
Author(s):  
Andrea C. Ortiz ◽  
Islavo Casas ◽  
Pablo Mella ◽  
Omar Naranjo ◽  
Nancy Pizarro ◽  
...  
Keyword(s):  
Tricarbonyl Complex ◽  
Lipid Core ◽  
Rhenium Tricarbonyl

scholarly journals Flexible to rigid: IR spectroscopic investigation of a rhenium-tricarbonyl-complex at a buried interface

2021 ◽  
Vol 23 (7) ◽  
pp. 4311-4316
Author(s):  
Kerstin T. Oppelt ◽  
Laurent Sevéry ◽  
Mirjam Utters ◽  
S. David Tilley ◽  
Peter Hamm
Keyword(s):  
Infrared Spectroscopy ◽  
Spectroscopic Investigation ◽  
Tricarbonyl Complex ◽  
Time Resolved ◽  
Time Resolved Infrared Spectroscopy ◽  
Ir Spectroscopic ◽  
Rhenium Tricarbonyl

Immobilized rhenium tricarbonyl complexes were embedded in ALD deposited ZrO2, and investigated by (time resolved) infrared spectroscopy. The initially solvent exposed molecules react on the change of their environment.

Application of the organometallic technetium and rhenium tricarbonyl complex on neuropeptide labelling

2001 ◽  
Vol 44 (S1) ◽  
pp. S556-S558 ◽  
Author(s):  
P. Bläuenstein ◽  
E. García Garayoa ◽  
A. Blanc ◽  
R. La Bella ◽  
P. A. Schubiger ◽  
...  
Keyword(s):  
Tricarbonyl Complex ◽  
Rhenium Tricarbonyl

scholarly journals Substitution reactivity and structural variability induced by tryptamine on the biomimetic rhenium tricarbonyl complex

RSC Advances ◽  
2021 ◽  
Vol 11 (39) ◽  
pp. 24443-24455
Author(s):  
Frederick J. F. Jacobs ◽  
Gertruida J. S. Venter ◽  
Eleanor Fourie ◽  
Robin E. Kroon ◽  
Alice Brink
Keyword(s):  
Bidentate Ligand ◽  
Tricarbonyl Complex ◽  
Structural Variability ◽  
Rhenium Tricarbonyl

The biomimetic tryptamine rhenium tricarbonyl complex shows rapid substitution reactivity on the 6th position as well as cytotoxicity and photoluminescence capability induced by the salicylidene bidentate ligand.

The role of zero-field splitting and π-stacking interaction of different nitrogen-donor ligands on the optical properties of luminescent rhenium tricarbonyl complexes

2021 ◽  
Author(s):  
Plinio Cantero-López ◽  
Yoan Hidalgo-Rosa ◽  
Zoraida Sandoval-Olivares ◽  
Julián Santoyo-Flores ◽  
Pablo Mella ◽  
...  
Keyword(s):  
Excited States ◽  
Coordination Compounds ◽  
Donor Ligands ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor ◽  
Π Stacking Interaction ◽  
Rhenium Tricarbonyl

Rhenium tricarbonyl complexes are one of the most important classes of coordination compounds in inorganic chemistry. Exploring their luminescent excited states, lowest singlet (S1), and the lowest triplet (T1), is...

scholarly journals Synthesis, Characterization, and Biological Studies of a Piperidinyl Appended Dipicolylamine Ligand and Its Rhenium Tricarbonyl Complex as Potential Therapeutic Agents for Human Breast Cancer

2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Amali Subasinghe ◽  
Inoka C. Perera ◽  
Svetlana Pakhomova ◽  
Theshini Perera
Keyword(s):  
Breast Cancer ◽  
Anticancer Agents ◽  
Human Breast Cancer ◽  
Human Breast ◽  
Tricarbonyl Complex ◽  
Nmr Spectrum ◽  
H Nmr ◽  
Biological Studies ◽  
Visible Spectra ◽  
Uv Visible

A novel ligand bearing a central piperidinyl sulfonamide group, N(SO2pip)dpa, and its corresponding Re tricarbonyl complex, [Re(CO)3(N(SO2pip)dpa)]+, have been synthesized in good yield. The methylene CH2signal seen as a singlet (4.54 ppm) in a1H NMR spectrum of the ligand in DMSO-d6appears as two doublets (5.39, 5.01 ppm) in a spectrum of the [Re(CO)3(N(SO2pip)dpa)]+complex and confirms the presence of magnetically nonequivalent protons upon coordination to Re. Structural results revealed that the Re–N bond lengths fall within the normal range establishing coordination of ligand to metal. The presence of intraligandπ→π⁎andn→π⁎transitions is indicated by the absorption peaks around 200–250 nm in UV-visible spectra. Absorption peaks in UV-visible spectra around 300 nm for metal complexes were identified as MLCT transitions. The S–N stretch observed as a strong peak at 923 cm−1for N(SO2pip)dpa appeared at a shorter frequency, at 830 cm−1in an FTIR spectrum of the [Re(CO)3(N(SO2pip)dpa)]+. The intense fluorescence displayed by the N(SO2pip)dpa ligand has quenched upon coordination to Re. Relatively low IC50values given by human breast cancer cells, MCF-7, (N(SO2pip)dpa = 139 μM, [Re(CO)3(N(SO2pip)dpa)]+= 360 μM) indicate that N(SO2pip)dpa and [Re(CO)3(N(SO2pip)dpa)]+are promising novel compounds that can be further investigated on their usage as potential anticancer agents.

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