Raman spectroscopic study of the structure of water in aqueous solutions of amphoteric polymers

2006 ◽  
Vol 8 (10) ◽  
pp. 1178 ◽  
Author(s):  
Hiromi Kitano ◽  
Kohei Takaha ◽  
Makoto Gemmei-Ide



2004 ◽  
Vol 707 (1-3) ◽  
pp. 83-88 ◽  
Author(s):  
Ruihua Li ◽  
Zhanpeng Jiang ◽  
Fengen Chen ◽  
Hongwei Yang ◽  
Yuntao Guan






1995 ◽  
Vol 50 (2-3) ◽  
pp. 292-300 ◽  
Author(s):  
Fernando Rull

Abstract A Raman spectroscopic study of Li2SO4 aqueous solutions as function of concentration and temperature was performed. The dynamic properties of the sulfate ions were studied by a band profile analysis of their internal modes using Fourier transform methods. This analysis reveals the perturbation of the SO4-2 vibrations due to ionic interactions. From the v1 (SO4-2) band profile the spectroscopic ionic association constant was calculated in the range from 5 to 80 °C. The large difference found between the values thus obtained for the association constant and the values obtained from macroscopic measurements is interpreted, assuming that Raman spectra reflect only the short-range forces acting on the ions. Using the Bjerrum equation to calculate the contribution for the long-range forces, good agreement is found between the spectroscopic and macroscopic results.



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