Dual-mode oxygen-sensing based on oxygen-adduct formation at cobaltporphyrin–polymer and luminescence quenching of pyrene: an optical oxygen sensor for a practical atmospheric pressure

2008 ◽  
Vol 18 (8) ◽  
pp. 917 ◽  
Author(s):  
Tsuyoshi Hyakutake ◽  
Ichiro Okura ◽  
Keisuke Asai ◽  
Hiroyuki Nishide
Author(s):  
YUTAKA AMAO ◽  
KEISUKE ASAI ◽  
ICHIRO OKURA

An optical oxygen sensor based on the phosphorescence quenching of palladium tetrakis(4-carboxyphenyl)porphyrin (PdTCPP) self-assembled film (SAM) on alumina plate was developed. The phosphorescence intensity of PdTCPP film decreased with increasing oxygen pressure, indicating that the film can be used as an optical oxygen-sensing device based on phosphorescence quenching by oxygen. The ratio I0/I100 as a sensitivity measure of the sensing film is estimated to be 17.7, showing that the film is a highly sensitive device for oxygen pressure. The film obeyed Stern–Volmer plots with a multisite model and possessed good operational stability and a fast response. Response times are 36 s for deoxygenated to oxygenated conditions and 148 s for the reverse conditions.


2009 ◽  
Vol 13 (11) ◽  
pp. 1111-1122 ◽  
Author(s):  
Yutaka Amao ◽  
Ichiro Okura

Oxygen-monitoring techniques are applied to various fields, such as chemicals, deep sea environment, fluid dynamics, clinical analysis and environmental monitoring. Recently, a variety of devices and sensors based on phosphorescence or photoexcited state quenching of porphyrin molecules have been developed to measure oxygen concentration on the solid surface. Many optical oxygen sensors are composed of porphyrins (platinum(II), palladium(II), zinc(II), metal-free, etc.) dispersed in oxygen-permeable polymer film or directly immobilized onto solid surface via chemical or physical adsorption. Oxygen-sensing systems are classified into four types: (1) phosphorescence intensity change, (2) phosphorescence lifetime change, (3) change of lifetime of photoexcited triplet state, and (4) intensity change of absorption of photoexcited triplet state. In this review, the properties of various optical oxygen-sensing devices using porphyrins and sensing system are introduced.


2003 ◽  
Vol 18 (12) ◽  
pp. 1439-1445 ◽  
Author(s):  
Kosuke Tsukada ◽  
Shuhei Sakai ◽  
Kentaro Hase ◽  
Haruyuki Minamitani

1994 ◽  
Vol 43 (11) ◽  
pp. 1139-1145 ◽  
Author(s):  
Shabbir B. Bambot ◽  
Raja Holavanahali ◽  
Joseph R. Lakowicz ◽  
Gary M. Carter ◽  
Govind Rao

2012 ◽  
Vol 180 (3-4) ◽  
pp. 311-318 ◽  
Author(s):  
Kristyna Pospiskova ◽  
Ivo Safarik ◽  
Marek Sebela ◽  
Gabriela Kuncova

2009 ◽  
Vol 108 ◽  
pp. S154
Author(s):  
Kevin Montagne ◽  
Kikuo Komori ◽  
Tetsu Tatsuma ◽  
Teruo Fujii ◽  
Yasuyuki Sakai

2018 ◽  
Vol 257 ◽  
pp. 944-953 ◽  
Author(s):  
Yongyun Mao ◽  
Zhipeng Mei ◽  
Jiayue Wen ◽  
Gang Li ◽  
Yanhong Tian ◽  
...  

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