Enantioselective transfer hydrogenation of ketone catalysed by artificial metalloenzymes derived from bovine β-lactoglobulin

2012 ◽  
Vol 48 (98) ◽  
pp. 11984 ◽  
Author(s):  
Alice Chevalley ◽  
Michèle Salmain
Keyword(s):  
Transfer Hydrogenation ◽  
Artificial Metalloenzymes ◽  
Β Lactoglobulin

Artificial metalloenzymes derived from bovine β-lactoglobulin for the asymmetric transfer hydrogenation of an aryl ketone – synthesis, characterization and catalytic activity

2014 ◽  
Vol 43 (14) ◽  
pp. 5482-5489 ◽  
Author(s):  
Alice Chevalley ◽  
Mickael V. Cherrier ◽  
Juan C. Fontecilla-Camps ◽  
Mahsa Ghasemi ◽  
Michèle Salmain
Keyword(s):  
Catalytic Activity ◽  
Fatty Acid ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
P Protein ◽  
Artificial Metalloenzymes ◽  
Diimine Complexes ◽  
Β Lactoglobulin ◽  
Aryl Ketone

Protein hybrids resulting from the supramolecular anchoring to bovine β-lactoglobulin of fatty acid-derived Rh(iii) diimine complexes catalysed the asymmetric transfer hydrogenation of trifluoroacetophenone with up to 32% ee.

scholarly journals Controlled Ligand Exchange Between Ruthenium Organometallic Cofactor Precursors and a Naïve Protein Scaffold Generates Artificial Metalloenzymes Catalysing Transfer Hydrogenation

2021 ◽  
Vol 60 (19) ◽  
pp. 10919-10927
Author(s):  
George S. Biggs ◽  
Oskar James Klein ◽  
Sarah L. Maslen ◽  
J. Mark Skehel ◽  
Trevor J. Rutherford ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Transfer Hydrogenation ◽  
Protein Scaffold ◽  
Artificial Metalloenzymes
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