Enantioselectivity in organo transition metal chemistry. An unprecedented ligand effect in π-allyl palladium chemistry

1988 ◽  
pp. 718-719 ◽  
Author(s):  
J.-P. Genêt ◽  
S. Jugé ◽  
J. Ruiz Montès ◽  
J.-M. Gaudin
Keyword(s):  
Transition Metal ◽  
Transition Metal Chemistry ◽  
Ligand Effect ◽  
Metal Chemistry ◽  
Palladium Chemistry

Transition metal chemistry in synthetically viable alkaline earth complexes M(Cp)3– (M = Ca, Sr, Ba)

2021 ◽  
Author(s):  
Bin Huo ◽  
Rui Sun ◽  
Bo Jin ◽  
Lingfei Hu ◽  
Jian-Hong Bian ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxidation State ◽  
Alkaline Earth ◽  
Transition Metal Chemistry ◽  
Metal Chemistry

We predicted the stable alkaline earth complexes M(Cp)3– (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the...

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