A stimuli-responsive orthogonal supramolecular polymer network formed by metal–ligand and host–guest interactions

2014 ◽  
Vol 50 (6) ◽  
pp. 722-724 ◽  
Author(s):  
Jiayi Zhan ◽  
Qi Li ◽  
Qiuyue Hu ◽  
Qianqian Wu ◽  
Cunmin Li ◽  
...  
Soft Matter ◽  
2018 ◽  
Vol 14 (42) ◽  
pp. 8529-8536 ◽  
Author(s):  
You-Ming Zhang ◽  
Yong-Fu Li ◽  
Hu Fang ◽  
Jun-Xia He ◽  
Bi-Rong Yong ◽  
...  

A novel pseudorotaxanes-type crosslinker of a supramolecular polymer network (WP5-PN) was constructed based on water-soluble pillar[5]arene (WP5) and naphthalene dimethylamine derivative (PN) via host-guest interactions.


2014 ◽  
Vol 2 (44) ◽  
pp. 9331-9341 ◽  
Author(s):  
Masayoshi Higuchi

Based on the metal–ligand or metal–metal interactions, metallo-supramolecular polymer films showed stimuli-responsive electro- and photo-chemical properties such as electrochromism.


2017 ◽  
Vol 8 (25) ◽  
pp. 3783-3787 ◽  
Author(s):  
Yuezhou Liu ◽  
Liqing Shangguan ◽  
Hu Wang ◽  
Danyu Xia ◽  
Bingbing Shi

A novel external stimuli-responsive supramolecular polymer network gel was fabricated by orthogonal Ag-coordination and pillar[5]arene-based host–guest interactions.


2018 ◽  
Vol 9 (11) ◽  
pp. 1293-1297 ◽  
Author(s):  
Li Shao ◽  
Jie Yang ◽  
Bin Hua

A novel 2,2′-bipyridine-bridged pillar[5]arene dimer was synthesized and further applied for constructing linear supramolecular polymers and supramolecular polymer network gels.


2019 ◽  
Vol 30 (12) ◽  
pp. 2299-2303 ◽  
Author(s):  
Zengjie Liu ◽  
Jiarui Wu ◽  
Chunyu Wang ◽  
Jie Yang ◽  
Yan Wang ◽  
...  

2020 ◽  
Vol 44 (29) ◽  
pp. 12531-12537 ◽  
Author(s):  
Tai-Bao Wei ◽  
Li-Hua Qi ◽  
Qin-Peng Zhang ◽  
Wen-Huan Zhang ◽  
Hong Yao ◽  
...  

A novel supramolecular polymer network gel has been successfully prepared via bi-pillar[5]arene and a tripodal guest, exhibiting multi-stimuli-responsiveness and efficient adsorption of organic dyes.


2017 ◽  
Vol 50 (15) ◽  
pp. 5759-5766 ◽  
Author(s):  
Yan Wang ◽  
Ming-Zhe Lv ◽  
Nan Song ◽  
Zeng-Jie Liu ◽  
Chunyu Wang ◽  
...  

2016 ◽  
Vol 2 (1) ◽  
pp. e1501297 ◽  
Author(s):  
Qian Zhao ◽  
Weike Zou ◽  
Yingwu Luo ◽  
Tao Xie

Stimuli-responsive materials with sophisticated yet controllable shape-changing behaviors are highly desirable for real-world device applications. Among various shape-changing materials, the elastic nature of shape memory polymers allows fixation of temporary shapes that can recover on demand, whereas polymers with exchangeable bonds can undergo permanent shape change via plasticity. We integrate the elasticity and plasticity into a single polymer network. Rational molecular design allows these two opposite behaviors to be realized at different temperature ranges without any overlap. By exploring the cumulative nature of the plasticity, we demonstrate easy manipulation of highly complex shapes that is otherwise extremely challenging. The dynamic shape-changing behavior paves a new way for fabricating geometrically complex multifunctional devices.


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