Myoglobin-catalyzed intermolecular carbene N–H insertion with arylamine substrates
Engineered variants of sperm whale myoglobin efficiently catalyze the insertion of α-diazo esters into the N–H bond of arylamines, featuring a combination of high chemoselectivity, elevated turnover numbers, and broad substrate scope.
1967 ◽
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pp. 7452-7460
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1990 ◽
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pp. 11788-11795
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