Structural characterization of environmentally relevant ternary uranyl citrate complexes present in aqueous solutions and solid state materials

2015 ◽  
Vol 44 (6) ◽  
pp. 2597-2605 ◽  
Author(s):  
Madeline Basile ◽  
Daniel K. Unruh ◽  
Erin Flores ◽  
Adam Johns ◽  
Tori Z. Forbes
Keyword(s):  
Solid State ◽  
Aqueous Solutions ◽  
Structural Characterization ◽  
Solid State Materials ◽  
Polynuclear Clusters ◽  
Insight Into

Structural characterization of U(vi) : (Al(iii), Fe(iii)) : citrate complexes provides insight into the formation of polynuclear clusters present in environmentally-relevant aqueous solutions.

A Methyl Group Bridging on Three Metal Atoms. Solid-State and Solution Structural Characterization of the [Re3(μ-H)3(μ3-CH3)(CO)9]-Anion

1999 ◽  
Vol 121 (10) ◽  
pp. 2307-2308 ◽  
Author(s):  
T. Beringhelli ◽  
G. D'Alfonso ◽  
M. Panigati ◽  
F. Porta ◽  
P. Mercandelli ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Characterization ◽  
Methyl Group ◽  
Metal Atoms

Synthesis and structural characterization of a magnesium phthalocyanine(3–) anion

2012 ◽  
Vol 16 (01) ◽  
pp. 154-162 ◽  
Author(s):  
Edwin W.Y. Wong ◽  
Daniel B. Leznoff
Keyword(s):  
Absorption Spectrum ◽  
Solid State ◽  
Single Crystal ◽  
Structural Characterization ◽  
Heterometallic Complex ◽  
State Structure ◽  
Solid State Structure ◽  
X Ray ◽  
X Ray Crystallography

The reduction of magnesium phthalocyanine (MgPc) with 2.2 equivalents of potassium graphite in 1,2-dimethoxyethane (DME) gives [K2(DME)4]PcMg(OH)(1) in 67% yield. Compound 1 was structurally characterized using single crystal X-ray crystallography and was found to be a monomeric, heterometallic complex consisting of a μ3-OH ligand that bridges a [MgIIPc3-]- anion to two potassium cations solvated by four DME molecules. An absorption spectrum of 1 confirms the Pc ligand is singly reduced and has a 3–charge. The solid-state structure of 1 does not indicate breaking of the aromaticity of the Pc ligand. Compound 1 is only the second Pc3- complex and the first reduced MgPc to be isolated and structurally characterized.

Manganese(i) poly(mercaptoimidazolyl)borate complexes: spectroscopic and structural characterization of Mn⋯H–B interactions in solution and in the solid state

2005 ◽  
pp. 171-180 ◽  
Author(s):  
Leigh A. Graham ◽  
Alison R. Fout ◽  
Karl R. Kuehne ◽  
Jennifer L. White ◽  
Bhaskar Mookherji ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Characterization ◽  
Borate Complexes

Spectroscopic and Structural Characterization of the CyNHC Adduct of B2pin2in Solution and in the Solid State

2011 ◽  
Vol 77 (1) ◽  
pp. 785-789 ◽  
Author(s):  
Christian Kleeberg ◽  
Andrew G. Crawford ◽  
Andrei S. Batsanov ◽  
Paul Hodgkinson ◽  
David C. Apperley ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Characterization
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